2014 Publications

• T, Harschneck, N. Zhou, E. F. Manley, S. J. Lou, X. Yu, M. R. Butler, A. Timalsina, R. Turrisi, M. A. Ratner, L. X. Chen, R. P. H. Chang, A. Facchetti, Marks, T.J., Substantial Photovoltaic Response and Morphology Tuning in Benzo[1,2-b:6,5b']dithiophene (bBDT) Molecular Donors. Chem. Commun., 2014.

• Li, Z.; Assary, R. S.; Atesin, A. C.; Curtiss, L. A.; Marks, T. J., Rapid Ether and Alcohol C-O Bond Hydrogenolysis Catalyzed by Tandem High-Valent Metal Triflate + Supported Pd Catalysts. J. Am. Chem. Soc., 2014, 136, 104-107.

• Jackson, N. E.; Savoie, B. M.; Kohlstedt, K. L.; Marks, T. J.; Chen, L. X.; Ratner, M. A., Structural and Conformational Dispersion in the Rational Design of Conjugated Polymers. Macromolecules, 2014, 47, 987-992.

• Savoie, B. M.; Rao, A.; Bakulin, A. A.; Gelinas, S.; Movaghar, B.; Friend, R. H.; Marks, T. J.; Ratner, M. A., Unequal Partnership: Asymmetric Roles of Polymeric Donor and Fullerene Acceptor in Generating Free Charge. Journal of the American Chemical Society, 2014, 136, 2876-2884.

• Huang, H.; Zhou, N.; Ortiz, R. P.; Chen, Z.; Loser, S.; Zhang, S.; Guo, X.; Casado, J.; Lopez Navarrete, J. T.; Yu, X.; Facchetti, A.; Marks, T. J., Alkoxy-Functionalized Thienyl-Vinylene Polymers for Field-Effect Transistors and All-Polymer Solar Cells. Adv. Funct. Mater., 2014, Ahead of Print.

• Jariwala, D.; Sangwan, V. K.; Lauhon, L. J.; Marks, T. J.; Hersam, M. C., Emerging Device Applications for Semiconducting Two-Dimensional Transition Metal Dichalcogenides. ACS Nano, 2014, 8, 1102-1120.

• Jariwala, D.; Sangwan, V. K.; Lauhon, L. J.; Marks, T. J.; Hersam, M. C., Carbon nanomaterials for electronics, optoelectronics, photovoltaics, and sensing. arXiv.org, e-Print Arch., Condens. Matter, 2014, 1-105.

• Ramanan, C.; Kim, C. H.; Marks, T. J.; Wasielewski, M. R., Excitation Energy Transfer within Covalent Tetrahedral Perylenediimide Tetramers and Their Intermolecular Aggregates. J. Phys. Chem., 2014, Ahead of Print.

• Steyrleuthner, R.; Di Pietro, R.; Collins, B. A.; Polzer, F.; Himmelberger, S.; Schubert, M.; Chen, Z.; Zhang, S.; Salleo, A.; Ade, H.; Facchetti, A.; Neher, D., The Role of Regioregularity, Crystallinity, and Chain Orientation on Electron Transport in a High-Mobility n-Type Copolymer. J. Am. Chem. Soc., 2014, 136, 4245-4256.

• Szarko, J. M.; Rolczynski, B. S.; Lou, S. J.; Xu, T.; Strzalka, J.; Marks, T. J.; Yu, L.; Chen, L. X., Photovoltaic Function and Exciton/Charge Transfer Dynamics in a Highly Efficient Semiconducting Copolymer. Adv. Funct. Mater., 2014, 24, 10-26.

• Zhou, N.; Buchholz, D. B.; Zhu, G.; Yu, X.; Lin, H.; Facchetti, A.; Marks, T. J.; Chang, R. P. H., Polymer Solar Cells: Ultraflexible Polymer Solar Cells Using Amorphous Zinc-Indium-Tin Oxide Transparent Electrodes Adv. Mater., 2014, 26, 1098-1104.

•  Zhou, N.; Lin, H.; Lou, S. J.; Yu, X.; Guo, P.; Manley, E. F.; Loser, S.; Hartnett, P.; Huang, H.; Wasielewski, M. R.; Chen, L. X.; Chang, R. P. H.; Facchetti, A.; Marks, T. J., Morphology-Performance Relationships in High-Efficiency All-Polymer Solar Cells. Adv. Energy Mater. 2014, 4, 1-8.

• McInnis, J. P.; Delferro, M.; Marks, T. J., Multinuclear Group 4 Catalysis: Olefin Polymerization Pathways Modified by Strong Metal–Metal Cooperative Effects. Accounts of Chemical Research. 2014, ASAP (DOI: 10.1021/ar5001633).

• Liu, S.; Motta, A.; Mouat, A.R.; Delferro, M.; Marks, T.J.; Very Large Cooperative Effects in Heterobimetallic Titanium-Chromium Catalysts for Ethylene Polymerization/Copolymerization. J.Am. Chem. Soc. 2014, 136, pp. 10460-10469.

• Jariwala, D.; Sangwan, V.K.; Lauhon, L.J.; Marks, T.J.; Hersam, M.C. Emerging Device Applications for Semiconducting Two-Dimensional Transition Metal Dichalcogenides (Review), ACS Nano, 2014,  8, 1102–1120.

• Zhou, N.; Lee, B.; Timalsina, A.; Guo, P.; Yu, X.; Marks, T.J.; Facchetti, A.; Chang, R.P.H. A Cross-Linkable Molecular Hole-Transporting Semiconductor for Solid State Dye Sensitized Solar Cells and the Effect of Additives, J. Phys. Chem. C. 2014, 118 , 16967–16975.

• Bassanetti, I.; Twist, C.P.; Kim, M.-G.; Seyam, A.M.; Bazzi, H.S.; Wang, Q.J.; Chung, Y.-W.; Marchio, L.; Delferro, M.; Marks, T.J. Synthesis and Characterization of Silver(I) Pyrazolylmethylpyridine Complexes and their Implementation as Metallic Silver Thin Film Precursors, Inorg. Chem. 2014,53, 4629–4638.

• Savoie, B.M.; Jackson, N.E.; Chen, L.X.; Marks, T.J.; Ratner, M.A. The Mesoscopic Features of Charge Generation in Organic Semiconductors, Accts. Chem. Res., 2014, 47, 3385-3394.

• Jackson, N.E.; Heitzer, H.M.; Savoie, B.M.; Reuter, M.G.; Marks, T.J.; Ratner, M.A. Emergent Properties in Locally Ordered Molecular Materials, Israel Journal of Chemistry, 2014, 54, 454 – 466 .

• McInnis, J.P.; Delferro, M.; Marks, T.J.; Multinuclear Catalysis: Olefin Polymerization Pathways Modified by Strong Cooperative Effects, Accts. Chem. Res., 2014, 47, 2545–2557.

• Youn, J.; Huang, P.-Y.; Zhang, S.; Liu, C.-W.; Stern, C.; Kim, C.; Chen, M.-C.; Facchetti, A.; Marks, T.J.; Functionalized Benzothieno [3,2-b] thiphenes (BTTs) High Preformance Organic Thin-Film Transistors (OTFTs), J. Mater. Chem. C. 2014, 2 (36).

• Heitzer, H.M.; Marks, T.J.; Ratner, M.A.; Maximizing the Dielectric Response of Molecular Films through Quantum Chemical Design, J. Amer. Chem. Soc. 2014, 136,  in press.

• Facchetti, A.; Ortiz, R.P.; Marks, T.J.; Self-Assembled Mono and Multilayers for Functional
Opto-Electronic Devices
, 2014, DOI:10.1039/9781782626947.

• Kim, I.S.; Jariwala, D.; Wood, J.D.; Park, S.; Chen, K.-S.; Shi, F.; Ruiz-Zepeda, F.; Ponce, A.; Jose-Yacaman, M.; Dravid, V.P.; Marks, T.J.; Hersam, M.C.; Lauhon, L.J.; Influence of Stoichiometry on the Optical and Electrical Properties of Chemical Vapor Deposition Derived MoS2, 2014, 8(10):10551-8.

• Bachrach, M.; Morlanes-Sanchez; N., Canlas; C. P.; Miller J. T.; Marks, T. J.; & Notestein, J. M.; Increasing the Aromatic Selectivity of Quinoline Hydrogenolysis Using Pd/MOx-Al2O3. Catal. Lett., 2014, 144(11), 1832-1838. doi: 10.1007/s10562-014-1346-x.

• Baeg, K.-J.; Kim, M.-G.; Song, C. K.; Yu, X.; Facchetti, A.; Marks, T. J.; Charge-trap flash-memory oxide transistors enabled by copper-zirconia composites. Adv Mater,2014,26(42), 7170-7177.

• Dudnik, A. S.; Weidner, V. L.; Motta, A.; Delferro, M.; Marks, T. J.; Organolanthanide-catalyzed atom-efficient and regioselective dearomatization of substituted aromatic N-heterocycles. Nature Chemistry, 2014, 6, 1100-1107.

• Jackson, N.E.; Savoie, B.M.; Kohlstedt, K.L.; Marks, T.J.; Chen, L.X.; Ratner, M.A. Structural and Conformational Isomers:  What is Hidden in the Rational Design of Conjugated Polymers, Macromolecules 2014, 47, 987–992.

• Ha, Y.-G.; Everaerts, K.; Hersam, M.C.; Marks, T.J. Hybrid Gate Dielectric Materials for Unconventional Electronic Circuitry, Accts. Chem. Res. 2014, 47, 1019–1028.

• Loser, S.; Valle, B.; Luck, K.A.; Song, C.K.; Ogien, G.; Hersam, M.C.; Singer, K.D.; Marks, T.J. High-Efficiency Inverted Polymer Photovoltaics via Spectrally Tuned Absorption Enhancement, , Advanced Energy Materials, 2014, DOI: 10.1002/aenm.201301938.

• Sangwan, V.K.; Jariwala, D.; Everaerts, K.; McMorrow, J.; He, J.; Grayson, M.; Lauhon, L.J.; Marks, T.J. and Hersam M.C. Wafer-Scale Solution-Derived Molecular Gate Dielectrics for Graphene Electronics, Appl. Phys. Lett. 2014, 104 , 083503.

• Heitzer, H.M.; Savoie, B.M.; Marks, T.J.; Ratner, M.A. Bridging Ultra-Fast and Diffusion-Limited Exciton Quenching Mechanisms in Organic Photovoltaics, Angew. Chem., 2014, 53, 7456–7460, DOI: 10.1002/anie.201402568.

• Savoie, B.M.; Kohlstedt, K.L. Jackson, N.E.; Chen, L.X.; Schatz, G.; Marks, Olvera, M. A.; T.J.; Ratner, M.A. A Description of the Molecular Networks that Carry Charge and the Sidechains that Disrupt Them, PNAS, 2014,111,10055-10060, DOI:10.1073/pnas.1409514111.

•  Huang, H.; Zhou, N.; Ortiz, R.P.; Chen, Z.; Loser, S.; Zhang, S.; Guo, X.; Casado, J.; Navarrete, J.T.L.; Yu, X.; Facchetti, A.; Marks, T.J. Alkoxy-Functionalized Thienyl-Vinylene Polymers for Field-Effect Transistors and All-Polymer Solar Cells, Advanced Functional Materials, 2014, 24, 2782–2793. DOI: 10.1002/adfm.201303219.

•   Luck, K.A.; Shastry, T.A.; Loser, S.; Ogden, G.; Marks, T.J.; Hersam, M.C. Improved Uniformity in High-Performance Organic Photovoltaics Enabled by (3-aminopropyl)triethoxysilane Cathode Functionalization, Phys. Chem. Chem. Phys., 2013, 15, 20966 - 20972.

•  Jariwala, D.; Sangwan, V.K.; Lauhon, L.J.; Marks, T.J.; Hersam, M.C. Emerging Device Applications for Semiconducting Two-Dimensional Transition Metal Dichalcogenides (Review), ACS Nano, 2014,  8, 1102–1120.

• Zhou, N.; Lee, B.; Timalsina, A.; Guo, P.; Yu, X.; Marks, T.J.; Facchetti, A.; Chang, R.P.H. A Cross-Linkable Molecular Hole-Transporting Semiconductor for Solid State Dye Sensitized Solar Cells and the Effect of Additives, J. Phys. Chem. C. 2014, 118 , 16967–16975.

• Harschneck, T.; Zhou, N.; Manley, E.F.; Lou, S.J.; Yu, X.; Butler, M.R.; Timalsina, A.; Turrisi, R.; Chen, L.X.; Chang, R.P.H.; Facchetti, A.; Marks, T.J. Substantial Photovoltaic Response and Morphology Tuning in Benzo[1,2-b:6,5-b’]dithiophene (bBDT) Molecular Donors, Chemical Communications, 2014, 50, 4099-4101 .

• Stephenson, C.J.; McInnis, J.P.; Chen, C.; Weberski Jr., M.P.; Motta, A.; Delferro, M.; Marks, T.J. Ni(II) Phenoxyiminato Olefin Polymerization Catalysis:  Striking Coordinative Modulation of Hyperbranched Polymer Microstructure and Stability by a Proximate Sulfonyl Group, ACS Catalysis, 2014, 4, 999-1004.

• Riano, A.; Burrezo, P.M.; Mancheno, M.J.; Timalsina, A.; Smith, J.; Facchetti, A.; Marks, T.J.; Navarrete, J.T.L.; Segura, J.L.; Casado, J.; Ponce Ortiz, R. High Performance Ambipolar Field-Effect Transistors Based on Dicyanovinyl-Substituted Diketopyrrolopyrrole Derivatives, J. Mater. Chem. C., 2014, 2, 6376-6386. DOI: 10.1039/C4TC00714J.

• Jackson, N.E.; Heitzer, H.M.; Savoie, B.M.; Reuter, M.G.; Marks, T.J.; Ratner, M.A. Emergent Properties in Locally Ordered Molecular Materials, Israel Journal of Chemistry, 2014, 54, 454 – 466.

• Savoie, B.M.; Dunaisky, S.; Marks, T.J.; Ratner, M.A. The Scope and Limitations of Ternary Blend Organic Photovoltaics, Adv. Energy Mater., 2014, Advanced Energy Materials. DOI: 10.1002/aenm.201400891.

• Song, C.K.; Luck, K.A.; Zhou, N.; Zeng, L.; Manley, E.; Heitzer, H.M.; Goldman, S.; Hersam, M.C.; Chang, R.P.H.; Bedzyk, M.J.; Chen, L.X.; Ratner, M.A.; Marks, T.J.; “Supersaturated” Self-Assembled Charge-Blocking Layers for Organic Solar Cells, 2014, J. Amer. Chem. Soc., 2014, 136, 17762–17773. DOI: 10.1021/ja508453n.

• Liu, S.; Motta, A.; Mouat, A.R.; Delferro, M.; Marks, T.J.; Remarkable Cooperative Effects in Heterobimetallic Titanium-Chromium Catalysts for Ethylene Polymerization/Copolymerization, J. Amer. Chem. Soc. 2014, 136, 10460–10469 .

• Heitzer, H.M.; Marks, T.J.; Ratner, M.A.; Maximizing the Dielectric Response of Molecular Films through Quantum Chemical Design, ACS Nano, 2014,  8 (12), 12587–12600. DOI: 10.1021/nn505431p.

• Song, C.K.; Eckstein, B.J.; Tam, T.J.D.; Lynn, T.; Marks, T.J.; Conjugated Polymer Energy Level Shifts in Lithium Ion Battery Electrolytes, ACS Appl. Mater. Interfaces, 2014, 6, 19347–19354; DOI: 10.1021/am505416m .

•  Lee, B.; Stoumpos, C.C.; Cao, D.; Zhou, N.; Hupp, J.T.; Marks, T.J.; Kanatzidis, M.G.; Chang, R.P.H; Air Stable Molecular Semiconducting Iodosalts For Solar Cell Applications: Cs2SnI6, As a Hole Conductor, J.Amer. Chem. Soc., 2014, 136, 15379–15385.

•  Kim, I.S.; Sangwan, V.K.; Jariwala, D.; Wood, J.D.; Park, S.; Chen, K-S.; Shi, F.; Ruiz-Zepeda, F.; Ponce, A.; Jose-Yacaman, M.; Dravid, V.P.; Marks, T.J.; Hersam, M.C.; Lauhon, L.; Influence of Stoichiometry on the Optical and Electrical Properties of Chemical Vapor Deposition Derived MoS2, ACS Nano, 2014, 8,10551–10558. DOI: 10.1021/nn503988x.

• Hsieh, H.-H.; Yu, X.; Xia, Y.; Sheets, C.W.; Hsiao, C.-C.; Marks, T.J.; Facchetti, A.; Novel Approaches for Fabricating High-Performance Low-Temperature Solution-Processed Metal Oxide Transistors, SID Digest 2014, 45, 427-430. DOI: 10.1002/j.2168-0159.2014.tb00115.x.


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