Marks Group Tobin Marks|Research|Publications|People&Photos|Meetings

Group Publications

A-Team (Organometallics)
B-Team (Molecular Photonics)
C-Team (MOCVD)
D-team (Molecular Electronics)
 

A-Team

  • Guo, N.; DiBenedetto, S.A.; Tewari, P.; Lanagan, M.T.; Ratner, M.A.; Marks, T.J. Catalytic In Situ Synthesis of High Energy Storage Density Metal Oxide-Polyolefin Nanocomposites Using Supported Metallocenes.  Systematics of Nanoparticle, Size, Shape, and Interfacial Characteristics on Leakage Current Density, Permittivity, and Breakdown Strength, submitted for publication.
  • Seo, S.Y.; Yu, X.; Marks, T.J. Intramolecular Hydroalkoxylation/Cyclization of Alkynyl Alcohols Mediated by Lanthanide Catalysts.  Scope and Reaction Mechanism, submitted for publication.
  • Salata, M.R.; Marks, T.J. Catalyst Nuclearity Effects in Olefin Polymerization.  Enhanced Activity and Incorporation of Comonomers in Ethylene + Olefin Copolymerizations Mediated by Bimetallic Group 4 Phenoxyiminato Catalysts, submitted for publication.
  • Rodriguez, B.A.; Delferro, M.; Marks, T.J. Neutral Binuclear Nickel Catalysts for Ethylene Polymerization in Polar Media and Ethylene Copolymerization with Functionalized Polar Comonomers, J. Am. Chem. Soc., in press.
  • Motta, A.; Fragala, I.L.; Marks, T.J. Proximity and Cooperativity Effects in Binuclear d0 Olefin Polymerization Catalysts.  Theoretical Analysis of Structure and Mechanism, submitted for publication.
  • Rodriguez, B.A.; Delferro, M.; Marks, T.J. Neutral Bimetallic Ni(II) Phenoxyiminato Catalysts for Highly Branched Polyethylenes and Ethylene-Norbornene Copolymerizations, Organometallics, 2008, 27, 2166-2168.
  • Dash, A.K.; Feng, H.; Stair, P.C.; Marks, T.J. Toward Single-Site Heterogeneous Oxidation Catalysts.  Selective Cyclohexane Oxidative Dehydrogenation using Variable-Nuclearity Organotitanium/Organovanadium Precursors Chemisorbed, submitted for publication.
  • Motta, A; Fragala, I.L.; Marks, T.J. Pathways for Chemisorptive Organozirconium Catalyst Activation and Reactivity on Oxide Surfaces.  A DFT Study for Dehydroxylated g-Alumina, J. Am. Chem. Soc., in press.
  • Seo, S.Y.; Marks, T.J. Mild Amidation of Aldehydes with Amines Mediated by Lanthanide Catalysts, Organic Letters, 2008, 10, 317-319.
  • Yuen, H.F.; Marks, T.J. Synthesis and Catalytic Properties of Phenylene-Bridged Binuclear Organolanthanide Complexes, Organometallics, 2008, 27, 155-158.
  • Salata, M.R.; Marks, T.J. Synthesis, Characterization, and Marked Polymerization Selectivity Characteristics of Binuclear Phenoxyiminato Organozirconium Catalysts, J. Am. Chem. Soc., 2008, 130, 12-13.
  • Amin, S.B.; Marks, T.J. Organo-fn,d0-Mediated Synthesis of Amine-Capped Polyethylenes.  Scope and Mechanism, Organometallics, 2008, 27, 2411-2420.
  • Guo, N.; Stern, C.L.; Marks, T.J. Bimetallic Effects in Homopolymerization of Styrene and Copolymerization of Ethylene and Styrenic Comonomers.  Scope, Kinetics, and Mechanism, J. Am. Chem. Soc., 2008, 130, 2246-2261.
  • Amin, S.B.; Marks, T.J. Versatile Routes to In Situ Polyolefin Functionalization with Heteroatoms.  Catalytic Chain Transfer, Angew. Chem. Int. Ed., 2008, 47, 2006-2025.
  • Amin, S.B.; Marks, T.J. Organolanthanide-Catalyzed Synthesis of Amine-Capped Polyethylenes, J. Am. Chem. Soc., 2007, 129, 10102-10103.
  • Book:  The Future of U.S. Chemistry Research, Benchmarks and Challenges, Casey, C.P.; Aizenberg, J.; Anderson, P.S.; Brus, L.E.; Ceyer, S.T.; Choppin, G.R.; Fenselau, C.C.; Fowler, J.S.; Francisco, J.S.; Long, T.E.; Marks, T.J.; Parrinello, M.; Wong, C.-H., National Academies Press, Washington, D.C., 2007.
  • Marks, T. J. Retrospective.  Frank Albert Cotton (1930-2007), Science, 2007, 316, 214.
  • Stubbert, B.D.; Marks, T.J. Constrained Geometry Organoactinides as Catalysts for Intramolecular Hydroamination/Cyclization.  A Mechanistic Analysis, J. Am. Chem. Soc., 2007, 129, 6149-6167.
  • Dzudza, A.; Marks, T.J. Lanthanide Triflate Catalyzed Friedel-Crafts Acylation.  A Kinetic and Mechanistic Study, J. Org. Chem., 2008, 73, 4004-4016.
  • Amin, S.B.; Marks, T.J. Organosilane Effects on Organotitanium-Catalyzed Styrene Polymerization, Organometallics, 2007, 26, 2960-2963.
  • Yu, X.; Seo, S.; Marks, T.J. Effective, Selective Hydroalkoxylation/Cyclization of Alkynyl and Allenyl Alcohols Mediated by Lanthanide Catalysts, J. Am. Chem. Soc., J. Am. Chem. Soc., 2007, 129, 7244-7245.
  • Motta, A.; Fragala, I.L.; Marks, T.J. Stereochemical Control Mechanisms in Propylene Polymerization Mediated by C1-Symmetric CGC Titanium Catalyst Centers, J. Amer. Chem. Soc., J. Amer. Chem. Soc., 2007, 129, 7327-7338.
  • Amin, S.B.; Marks, T.J. Alkenylsilane Effects on Mononuclear and Binuclear Organotitanium-Mediated Ethylene Polymerization: Scope and Mechanism of Simultaneous Polyolefin Branch and Functional Group Introduction, J. Am. Chem. Soc., 2007, 129, 2938-2953.
  • Guo, N.; DiBenedetto, S.A.; Kwon, D.-K.; Wang, L.; Russell, M.T.; Lanagan, M.T.; Facchetti, A.; Marks, T.J. Supported Metallocene Catalysis for in Situ Synthesis of High Energy Density Metal Oxide Nanocomposites, J. Amer. Chem. Soc., 2007, 129, 766-767.
  • Stubbert, B.D.; Marks, T.J. Constrained Geometry Organoactinides as Versatile Catalysts for the Intramolecular Hydroamination/Cyclization of Primary and Secondary Amines Having Diverse Tethered C-C Unsaturation, J. Am. Chem. Soc., 2007, 129, 4253-4271.
  • Yu, X.; Marks, T.J. Organophosphine Oxide-Substituted Lanthanide Binaphtholate Catalysts for Enantioselective Hydroamination/Cyclization, Organometallics, in press.
  • Marks, T.J. Editor, Special Feature on Polymerization, Proc. Nat. Acad. Sci., 2006, 103, 15288. Also therein: Li, H.; Marks, T.J. Nuclearity and Cooperativity Effects in Binuclear Catalysts and Cocatalysts for Olefin Polymerization. Strategies to Modify Polyolefin Architecture, Proc. Nat. Acad. Sci., 2006, 103, 15295-15302.
  • Zhao, J.; Marks, T.J. Recyclable Polymer-Supported Organolanthanide Hydroamination Catalysis. Preparation and Activation via Dynamic Transamination, Organometallics, 2006, 25, 4763-4772.
  • Motta, A.; Fragala, I.L.; Marks, T.J. Organolanthanide-Catalyzed Hydroamination/Cyclization Reactions of Amminoalkynes. Computational Investigation of Mechanism, Lanthanide Identity, and Substituent Effects for a Very Exothermic C-N Bond-Forming Process, Organometallics, 2006, 25, 5533-5539.
  • Roberts, J.A.S.; Chen, M.-C.; Seyam, A.M.; Li, L.; Zuccaccia, C.; Stahl, N.G.; Marks, T.J. Diverse Stereocontrol Effects Induced by Weakly Coordinating Anions.  Mono- and Polynuclear Halo-Perfluoroarylmetallates as Cocatalysts for Stereospecific Olefin Polymerization at Archetypal Cs- and C1-Symmetrical Catalysts, J. Am. Chem. Soc., 2007, 129, 12713-12733.
  • Li, H.; Li, L.; Schwartz, D.J.; Stern, C.L.; Marks, T.J. Coordination Copolymerization of Severely Encumbered Isoalkenes with Ethylene: Enhanced Enchainment Mediated by Binuclear Catalysts and Cocatalysts, J. Am. Chem. Soc., 2005, 127, 14756-14768.
  • Li, H.; Stern, C.L.; Marks, T.J. Significant Proximity and Cocatalyst Effects in Binuclear Catalysts for Olefin Polymerization, Macromolecules, 2005, 38, 9015-9027.
  • Motta, A.; Fragala, I.L.; Marks, T.J. Energetics and Mechanism of Organolanthanide-Mediated Phosphinoalkene Hydrophosphination/Cyclization. A Density Functional Theory Analysis, Organometallics, 2005, 24, 4995-5003.
  • Kawaoka, A.M.; Marks, T.J. Organolanthanide-Catalyzed Synthesis of Phosphine-Terminated Polyethylenes.  Scope and Mechanism, J. Am. Chem. Soc., in press.
  • Wang, J.; Li, H.; Guo, N.; Li, L.; Stern, C.L.; Marks, T.J. Covalently Linked Heterobimetallic Catalysts for Olefin Polymerization, Organometallics, 2004, 23, 5112-5114.
  • Seyam, A.M.; Stubbert, B.D.; Jensen, T.R.; O’Donnell III, J.J.; Stern, C.L.; Marks, T.J. Organolanthanide Constrained Geometry Complexes Modified for Catalysis.  Synthesis, Structure, and Aminoalkene Hydroamination Properties of a Pyrrolidine-Substituted Constrained Geometry Organolutetium Complex, Inorg. Chim. Acta, 2004, 357, 4029-4035.
  • Nicholas, C.P.; Marks, T.J. Sulfated Tin Oxide Nanoparticles as Supports for Molecule-Based Olefin Polymerization Catalysis, Nano Letters, 2004, 4, 1557-1559.
  • Kawaoka, A.M.; Marks, T.J. Organolanthanide-Catalyzed Synthesis of Phosphine-Capped Polyethylenes, J. Am. Chem. Soc., 2004, 126, 12764-12765.
  • Nicholas, C.P.; Marks, T.J. Zirconium Hydrocarbyl Chemisorption on Sulfated Metal Oxides.  Novel Supports, Chemisorption Pathways and Catalysis, Langmuir, 2004, 20, 9456-9462.
  • Hong, S.; Marks, T.J. New Developments in Organolanthanide-Mediated Hydroamination Catalysis, Accts. Chem. Res., 2004, 37, 673-686.
  • Guo, N.; Li, L.; Marks, T.J. Bimetallic Catalysis for Styrene Homopolymerization and Ethylene-Styrene Copolymerization. Exceptional Comonomer Selectivity and Insertion Regiochemistry, J. Am. Chem. Soc., 2004, 126, 6542-6543.
  • Motta, A.; Lanza, G.; Fragalà, I.L.; Marks, T.J. Energetics and Mechanism of Organolanthanide-Mediated Aminoalkene Hydroamination/Cyclization. A Density Functional Theory Analysis, Organometallics, 2004, 23, 4097-4104.
  • Li, H.; Li, L.; Marks, T.J. Nuclearity Effects in Olefin Polymerization.  Significantly Enhanced Polyethylene Molecular Weight and Comonomer Enchainment in Polymerizations Mediated by Binuclear Catalysts, Angew. Chem. Int. Ed., 2004, 43, 4937-4940.
  • Stubbert, B.D.; Stern, C.L.; Marks, T.J. Synthesis and Catalytic Characteristics of Novel Constrained Geometry Organoactinide Catalysts. The First Example of Actinide-Mediated Intramolecular Hydroamination, Organometallics, 2003, 22, 4836-4838.
  • Chen, M.-C.; Roberts, J.A.; Marks, T.J. New Mononuclear and Polynuclear Perfluoroarylmetallate Cocatalysts for Stereospecific Olefin Polymerization, Organometallics, 2004, 5, 932-935.
  • Dash, A.K.; Jensen, T.R.; Stern, C.L.; Marks, T.J.Frustrated b-Chloride Elimination. Selective Arene Alkylation of a-Chloronorbornene Catalyzed by Electrophilic Metallocenium Ion-Pairs, J. Am. Chem. Soc., 2004, 126, 12528-12540.
  • Zuccaccia, C.; Stahl, N.G.; Macchioni, A.; Chen, M.-C.; Roberts, J.A.; Marks, T.J. NOE and PGSE NMR Spectroscopic Studies of Solution Structure and Aggregation in Metallocenium Ion-Pairs, J. Am. Chem. Soc., 2004, 126, 1448-1464.
  • Li, H.; Li, L.; Marks, T.J. Catalyst/Cocatalyst Nuclearity Effects in Single-Site Olefin Polymerization. Significantly Enhanced 1-Octene and Isobutene Comonomer Enchainment in Ethylene Polymerizations Mediated by Binuclear Catalysts and Cocatalysts, J. Am. Chem. Soc., 2003, 125, 10788-10789.
  • Jensen, T.R.; O’Donnell III, J.J.; Marks, T.J. d0/fn-Mediated Ring-Opening Ziegler Polymerization (ROZP) and Copolymerization with Mono- and Disubstituted Methylenecyclopropanes. Diverse Mechanisms and a New Chain-Capping Termination Process, Organometallics, 2004, 23, 740-754.
  • Jensen, T.R.; Yoon, S.C.; Dash, A.K.; Luo, L.; Marks, T.J. Organo-Titanium Mediated Stereoselective Coordinative/Insertive Homopolymerizations and Copolymerizations of Styrene and Methyl Methacrylate, J. Am. Chem. Soc., 2003, 125, 14482-14494.
  • Hong, S.; Tian, S.; Metz, M.V.; Marks, T.J. C2-Symmetric Bis(oxazolinato) Lanthanide Catalysts for Enantioselective Intramolecular Hydroamination/Cyclization, J. Am. Chem. Soc., 2003, 125, 14768-14783.
  • Ryu, J.-S.; Marks, T.J.; McDonald, F.E. Organolanthanide-Catalyzed Intramolecular Hydroamination/Cyclization/Bicyclization of Sterically Encumbered Substrates. Scope, Selectivity, and Catalyst Thermal Stability for Amine-Tethered Unactivated 1,2-Disubstituted Alkenes, J. Org. Chem., 2004, 69, 1038-1052.
  • Hong, S.; Kawaoka, A.M.; Marks, T.J. Intramolecular Hydroamination/Cyclization of Conjugated Aminodienes Catalyzed by Organolanthanide Complexes. Scope, Diastereo- and Enantioselectivity, and Reaction Mechanism, J. Am. Chem. Soc., 2003, 125, 15878-15892.
  • Jensen, T.R.; Marks, T.J. Diversity of Pathways in Ring-Opening Ziegler Polymerization. A New Single-Site Chain Transfer Mechanism, Macromolecules, 2003, 36, 1775-1778.
  • Kawaoka, A.M.; Douglass, M.R.; Marks, T.J. Homoleptic Lanthanide Amide and Alkyl Precatalysts Efficiently Mediate Intramolecular Hydrophosphination/Cyclization. Observations on Scope and Mechanism, Organometallics, 2003, 22, 4030-4032.
  • Ryu, J.; Li, Y.; Marks, T.J. Organolanthanide-Catalyzed Regiospecific Intermolecular Hydroamination of Alkenes, Vinylarenes, Di/trivinylarenes, and Methylenecyclopropanes. Scope and Mechanistic Comparison to Intramolecular Cyclohydroaminations, J. Am. Chem. Soc., 2003, 125, 12584-12605.
  • Chen, M-C.; Roberts, J.A.; Marks, T.J. Marked Counteranion Effects on Single-Site Olefin Polymerization Processes. Correlations of Ion Pair Structure and Dynamics with Polymerization Activity, Chain Transfer Pathways, and Syndioselectivity, J. Am. Chem. Soc., 2004, 126, 4605-4625.
  • Stahl, N.G.; Zuccaccia, C.; Jensen, T.R.; Marks, T.J. Metallocene Polymerization Catalyst Ion-Pair Aggregation by Cryoscopy and Pulsed Gradient Spin-Echo NMR Diffusion Measurements, J. Am. Chem. Soc., 2003, 125, 5256-5257.
  • Nicholas, C.P.; Ahn, H.; Marks, T.J. Synthesis, Spectroscopy, and Catalytic Properties of Cationic Organozirconium Adsorbates on "Super Acidic" Sulfated Alumina. "Single-Site" Heterogeneous Catalysts with Virtually 100% Active Sites, J. Amer. Chem. Soc, 2003, 125, 4325-4331.
  • Abramo, G.P.; Li, L.; Marks, T.J. Polynuclear Catalysis. Enhancement of Enchainment Cooperativity Between Different Single-Site Olefin Polymerization Catalysts by Ion Pairing with a Binuclear Co-Catalyst, J. Am. Chem. Soc., 2002, 124, 13966-13967.
  • Lanza, G.; Fragala, I.L.; Marks, T.J. Energetic, Structural, and Dynamic Aspects of Ethylene Polymerization Mediated by Homogeneous Single-Site "Constrained Geometry Catalysts" in the Presence of Cocatalyst and Solvation: An Investigation at the ab Initio Quantum Chemical Level, Organometallics, 2002, 21, 5594-5612.
  • Metz, M.V.; Sun, Y.; Stern, C.L.; Marks, T.J. Weakly Coordinating Al-, Nb-, Ta-, Y-, and La-Based Perfluoroaryloxide Anions as Cocatalyst Components for Single-Site Olefin Polymerization, Organometallics, 2002, 21, 3691-3702.
  • Metz, M.V.; Schwartz, D.J.; Stern, C.L.; Marks, T.J. New Perfluoroarylborane Activators for Single-Site Olefin Polymerization. Acidity and Cocatalytic Properties of a "Superacidic" Perfluorodiboraanthracene, Organometallics, 2002, 21, 4159-4168.
  • Ahn, H.; Marks, T.J. High-Resolution Solid-State 13C NMR Structural Studies of Chemisorbed Organometallics. Chemisorptive Formation of Organotantalum Cationic and Alkylidene Complexes on High-Surface Area Inorganic Oxides, J. Am.Chem. Soc., 2002, 124, 7103-7110.
  • Ahn, H.; Nicholas, C.P.; Marks, T.J. Surface Organozirconium Complexes Activated by Chemisorption on "Super Acidic" Sulfated Zirconia as Hydrogenation and Polymerization Catalysts. A Synthetic, Structural, and Mechanistic Catalytic Study, Organometallics, 2002, 21, 1788-1806.
  • Hong, S.; Marks, T.J. Intramolecular Hydroamination/Cyclization of Aminodienes. Scope and Selectivity, J. Am. Chem. Soc., 2002, 124, 7886-7887.
  • Li, L.; Metz, M.V.; Li, H.; Chen, M.-C.; Marks, T.J.; Liable-Sands, L.; Rheingold, A.L. Catalyst/Cocatalyst Nuclearity Effects in Single-Site Polymerization. Significantly Enhanced Polyethylene Branching and α-Olefin Comonomer Enchainment in Polymerizations Mediated by Binuclear Catalysts and Cocatalysts, J. Am. Chem. Soc., 2002, 124, 12725-12741
  • Chen, M-C.; Marks, T.J. Strong Ion Pairing Effects on Single-Site Olefin Polymerization. Mechanistic Insights in Syndiospecific Propylene Enchainment, J. Amer. Chem. Soc., 2001, 123, 11803-11804.
  • Douglass, M.R.; Ogasawara, M.; Hong, S.; Metz, M.V.; Marks, T.J. "Widening the Roof:" Synthesis and Characterization of New Chiral C1-Symmetric Octahydrofluorenyl Organolanthanide Catalysts and Their Implementation in the Stereoselective Cyclizations of Aminoalkenes and Phosphinoalkenes, Organometallics, 2002, 21, 283-292.
  • Ryu, J.-S.; Marks, T.J.; McDonald, F.E. Organolanthanide-Catalyzed Intramolecular Hydroamination/Cyclization of Amines Tethered to 1,2-Disubstituted Alkenes, Organic Letters, 2001, 3, 3091-3094.
  • Douglass, M.R.; Marks, T.J. Intramolecular Hydrophosphination/Cyclization of Phosphinoalkenes and Phosphinoalkynes Catalyzed by Organolanthanides. Scope, Selectivity, and Mechanism, J. Amer. Chem. Soc., 2001, 123, 10221-10238.
  • Makio, H.; Koo, K.; Marks, T.J. Silanolytic Chain Transfer in Olefin Polymerization with Supported Single-Site Ziegler-Natta Catalysts, Macromolecules, 2001, 34, 4676-4679.
  • Lanza, G.; Fragala I.L.; Marks, T.J. Metal and Ancillary Ligand Structural Effects on Ethylene Insertion Processes at Cationic Group 4 Centers. A Systematic, Comparative Quantum Chemical Investigation at Various Ab Initio Levels, Organometallics, 2001, 20, 4006-4017.
  • Aresta, M.; Armor, J.N.; Barteau, M.A.; Beckman, E.J.; Bell, A.T.; Bercaw, J.E.; Creutz, C.; Dinjus, E.; Dixon, D.A.; Domen, K.; Dubois, D.L.; Eckert, J.; Fujita, E.; Gibson, D.H.; Goddard, W.A.; Goodman, D.W.; Keller, J.; Kubas, G.J.; Kung, H.H.; Lyons, J.E.; Manzer, L.E.; Marks, T.J.; Morokuma, K.; Nicholas, K.M.; Periana, R.; Que, L.; Rostrup-Nielson, J.; Sachtler, W.M.H.; Schmidt, L.D.; Sen, A.; Somorjai, G.A; Stair, P.C.; Stults, B.R.; Tumas, W. Opportunities for Catalysis Research in Carbon Management, Chem. Rev., 2001, 101, 953-996.
  • Lanza, G.; Fragala, I.; Marks, T.J. Ligand Substituent, Anion, and Solvation Effects on Ion-Paired Structure, Thermodynamic Stability, and Structural Mobility in "Constrained Geometry" Olefin Polymerization Catalysts. An Ab Initio Quantum Chemical Investigation, J. Amer. Chem. Soc., 2000,122, 12764-12777.
  • Li, L.; Stern, C.L.; Marks, T.J. Bis(Pentafluorophenyl)(Perfluorobiphenyl)Borane. A New Perfluoroarylborane Cocatalyst for Single-Site Olefin Polymerization, Organometallics, 2000, 19, 3332.
  • Beswick, C.L.; Marks, T.J. Metal-Alkyl Group Effects on the Thermodynamic Stability and Stereochemical Mobility of B(C6F5)3-Derived Zr and Hf Metallocenium Ion-Pairs, J. Amer. Chem. Soc., 2000, 122, 10358-10370.
  • Li, L.; Metz, M.V.; Marks, T.J.; Liable-Sand, L.; Rheingold, A.L. Binuclear Constrained Geometry Catalysts and Binuclear Bisborate Cocatalysts for Olefin Polymerization, Polym. Prepr., 2000, 41 (2), 1912.
  • Li, L.; Stern, C.L.; Marks, T.J. Bis(Pentafluorophenyl)(Perfluorobiphenyl)Borane. A New Perfluoroarylborane Cocatalyst for Single-Site Olefin Polymerization, Organometallics, 2000, 19, 3332.
  • Douglass, M.R.; Marks, T.J. Organolanthanide-Catalyzed Intramolecular Hydrophosphination/Cyclization of Phosphinoalkenes and Phosphinoalkynes, J. Am. Chem. Soc., 2000, 122, 1824-1825.
  • Chen, E.Y.-C.; Marks, T.J. Co-Catalysts for Metal-Catalyzed Olefin Polymerization. Activators, Activation Processes, and Structure-Activity Relationships, Chem. Rev., 2000, 100, 1391-1434.
  • Metz, M.V.; Schwartz, D.J.; Stern, C.L.; Nickias, P.C.; Marks, T.J. New Highly Lewis Acidic Perfluoroaryldiboranes. Synthesis, Characterization, and Polymerization Cocatalytic Properties of Perfluoro-9,10-diboraanthracene, Angew. Chem. Int. Ed. Engl., 2000, 39, 1312-1316.
  • Sun, Y.; Metz, M.V.; Stern, C.L.; Marks, T.J. Al-, Nb-, and Ta-Based Perfluoroaryloxide Anions as Cocatalysts for Metallocene-Mediated Ziegler-Natta Olefin Polymerization, Organometallics, 2000, 19, 1625-1627.
  • Arredondo, V.M.; McDonald, F.E.; Marks, T.J. Intramolecular Hydroamination/Cyclization of Aminoallenes Catalyzed by Organolanthanide Complexes. Scope and Mechanistic Aspects, Organometallics, 1999, 18, 1949-1960.
  • Koo, K.; Marks, T.J. Silicon Modified Ziegler-Natta Polymerization. Catalytic Approaches to Silyl-Capped and Silyl-Linked Polyolefins Using "Single-Site" Cationic Zielger-Natta Catalysts, J. Am. Chem. Soc., 1999, 121, 8791.
  • Beswick, C.L.; Marks, T.J. Significant Zr-Alkyl Group Effects on Ion Pair Formation Thermodynamics and Structural Reorganization Dynamics in Zirconcenium Alkyls, Organometallics, 1999, 18, 2410-2412.
  • Tian, S.; Arredondo, V.M.; Stern, C.L.; Marks, T.J. Constrained Geometry Organolanthanide Catalysts. Synthesis, Structural Characterization, and Enhanced Aminoalkene Hydroamination/Cyclization Activity, Organometallics, 1999, 18, 2568.
  • Koo, K.; Marks, T.J. New, Efficient Routes to Functionalized Polyolefins. Catalytic Approaches to Silyl-Capped and Silyl-Linked Polyolefins Using "Single-Site" Organolanthanide and Cationic Ziegler-Natta Catalysts, CHEMTECH, 1999, October, 13.
  • King, W. A.; Di Bella S.; Gulino, A.; Lanza, G.; Fragalà, I. L.; Marks, T.J.; Stern, C. L. Absolute Metal-Ligand Sigma Bond Enthalpies in Group 4 Metallocenes: A Thermochemical, Structural, Photoelectron Spectroscopic, and ab initio Quantum Chemical Investigation J. Am. Chem. Soc., 1999, 121, 355.
  • Arredondo, V. M.; Marks, T.J.; McDonald, F. E. Organolanthanide-Catalyzed Hydroamination/Cyclization: Efficient Allene-Based Transformations for the Syntheses of Naturally Occurring Alkaloids, J. Am. Chem. Soc., 1999, 121, 3633.
  • Koo, K.; Marks, T.J.; Fu,P.-F. Organolanthanide-Mediated Silanolytic Chain Transfer Processes: Scope and Mechanism of Single Reactor Catalytic Routes to Silapolyolefins, Macromolecules, 1999, 32, 981.
  • Luo, L.; Di Bella, S.; Lanza, G.; Fragalà, I.L.; Stern, C.L.; Marks, T.J. Energetics of Metal-Ligand Multiple Bonds. A Combined Solution Thermochemical and ab initio Quantum Chemical Study of M=O Bonding In Group 6 Metallocene Oxo Complexes, J. Am. Chem. Soc., 1998, 120, 3111.
  • Koo, K.; Marks, T.J. Silanolytic Chain Transfer in Cationic Group 4 Metallocene-Mediated Olefin Polymerizations and Copolymerizations, J. Am. Chem. Soc., 1998, 120, 4019.
  • Li, Y.; Marks, T.J. Organolanthanide-Catalyzed Intra- and Intermolecular Tandem C-N, C-C Bond-Forming Processes of Amino-Dialkenes, Amino-Dialkynes, Amino-Alkene-Ynes, and Amino-Alkynes. New Regiospecific Approaches to Pyrrolizidine, Indolizidine, Pyrrole, and Pyrazine Skeletons, J. Am. Chem. Soc., 1998, 120, 1757.
  • Deck, P.A.; Beswick, C.L.; Marks, T.J. Highly Electrophilic Olefin Polymerization Catalysts. Quantitative Reaction Coordinates for Fluoroarylborane/Alumoxane Methide Abstraction and Ion Pair Reorganization in Group 4 Metallocene and "Constrained Geometry" Catalysts, J. Am. Chem. Soc., 1998, 120, 1772.
  • Chen, Y.-X.; Metz, M.V.; Stern, C.L.; Marks, T.J. Sterically Encumbered (Perfluoroaryl) Borane and Aluminate Cocatalysts for Tuning Cation-Anion Ion Pair Structure and Reactivity in Metallocene Polymerization Processes. A Synthetic, Structural, and Polymerization Study, J. Am. Chem. Soc., 1998, 120, 6287.
  • Arredondo, V.M.; McDonald, F.E.; Marks, T.J. Organolanthanide-Catalyzed Intramolecular Hydroamination/Cyclization of Aminoallenes, J. Am. Chem. Soc., 1998, 120, 4871.
  • Li, L.; Marks, T.J. New Organo-Lewis Acids. Tris(-Perfluoronaphthyl)Borane (PNB) As a Highly Active Cocatalyst for Metallocene-Mediated Ziegler-Natta Olefin Polymerization, Organometallics, 1998, 17, 3996.
  • Lanza, G.; Fragalà, I.L.; Marks, T.J. Highly Electrophilic Olefin Polymerization Catalysts. Counteranion and Solvent Effects on Constrained Geometry Catalyst Ion Pair Structure and Reactivity, J. Am. Chem. Soc., 1998, 120, 8257.
  • Ahn, H.; Marks, T.J. Supported Organometallics. Highly Electrophilic Cationic Metallocene Hydrogenation and Polymerization Catalysts Formed Via Protonolytic Chemisorption on Sulfated Zirconia, J. Am. Chem. Soc., 1998, 120, 13533.
 

B-Team

  • Wang, Y.; Fratterelli, D.L.; Facchetti, A.; Cariati, E.; Righetto, S.; Ugo, R.; Zuccaccia, C.; Macchioni, A.; Stern, C.L.; Ratner, M.A.; Marks, T.J. Twisted p-Electron System Electro-Optic Chromophores.  Structural and Electronic Consequences of Relaxing Twist-Inducing Non-Bonded Repulsions, J. Phys. Chem. C., 2008, 112, 3005-3015.
  • Li, J.; Liu, J.; Evmenenko, G.A.; Dutta, P.; Marks, T.J. Characterization of Transparent Conducting Oxide Surfaces Using Self-Assembled Electroactive Monolayers, Langmuir, 2008, 24, 5755-5765.
  • Li, J.; Liu, J.; Wang, L.; Marks, T.J.; Hu, L.; Grüner, G. Highly Transparent and Conductive Carbon Nanotube-Indium Tin Oxide Double-Layer Thin Film as Anode for Organic Light-Emitting Diodes, submitted for publication.
  • Li, J.; Marks, T.J. Air-Stable, Cross-Linkable Hole-Injecting/Transporting Interlayers for Improved Charge Injection in Organic Light-Emitting Diodes, Chem. Mater., in press.
  • Leever, B.J.; Pingree, L.S.C.; Hains, A.W.; Irwin, M.D.; Marks, T.J.; Hersam, M.C. Atomic Force Photovoltaic Microscopy, Appl. Phys. Lett., 2008, 92, 013302.
  • Wu, S.; Yi, F.; Liu, B.; Huang, Y.; Ho, S.T.; Wang, Y.; Liu, J.; Kang, H.; Marks, T.J.; Luo, J.; Tucker, N.; Jen, A.K.-Y. Transparent Conducting Oxide (TCO) Electrode Based High-Speed Organic Electro-Optic (EO) Modulator, CLEO Technical Digest (Optical Soc. Amer.) 2007, CMGG4.
  • Hains, A.W.; Marks, T.J. High-Efficiency Hole Extraction/Electron-Blocking Layer to Replace Poly (3,4-ethylenedioxythiophene):Poly (styrene sulfonate) (PEDOT:PSS) in Bulk-Heterojunction Polymer Solar Cells, Appl. Phys. Lett., 2008, 92, 023504.
  • Irwin, M.D.; Buchholz, D.B.; Hains, A.W.; Chang, R.P.H.; Marks, T.J. p-Type Semiconducting Nickel Oxide as an Efficiency-Enhancing Anode Interfacial Layer in Polymer Bulk-Heterojuction Solar Cells, Proc. Nat. Acad. Sci, 2008, 105, 2783-2787.
  • Hains, A.W.; Martinson, A.B.F.; Irwin, M.D.; Yan, H.; Marks, T.J. Bulk-Heterojunction Organic Solar Cells:  Interfacial Engineering Routes to Increased Open-Circuit Voltage and Power Conversion Efficiency, Poly. Mater.: Sci. & Eng, 2007, 96, 814.
  • Frattarelli, D.; Schiavo, M.; Facchetti, A.; Ratner, M.A.; Marks, T.J. Chromophore Fluorination and Hydrogen-Bonding Effects on the Electro-Optic Response of Thin-Films Grown from the Vapor Phase, submitted for publication.
  • Brown, E.C.; Marks, T.J.; Ratner, M.A. Nonlinear Response Properties of Ultra-Large Hyperpolarizability Twisted Donor-Acceptor Chromophores:  Dramatic Environmental Effects, J. Am. Chem. Soc., 2008, 112, 44-50.
  • Pingree, L.S.C.; Russell, M.T.; Marks, T.J.; Hersam, M.C. Probing Individual Nanoscale Organic Light-Emitting Diodes with Atomic Force Electroluminescence Microscopy and Bridge-Enhanced Nanoscale Impedance Microscopy, Organic Electronics, 2007, 8, 465-479.
  • Kang, H.; Facchetti, A.; Jiang, H.; Cariati, E.; Righetto, S.; Ugo, R.; Zuccaccia, C.; Macchioni, A.; Stern, C.L.; Marks, T.J. Ultra-Large Hyperpolarizability Twisted p-Electron System Electro-Optic Chromophores. Synthesis, Solid State and Solution Phase Structural Characteristics, Electronic Structures, Linear, and Nonlinear Optical Properties, J. Am. Chem. Soc., 2007, 129, 3267-3286.
  • Li, J.; Hu, L.; Zhou, Y.; Wang, L.; Grüner, G.; Marks, T.J. Organic Light-Emitting Diodes with Flexible Single-Walled Carbon Nanotube Film Anodes, NanoLetters, 2006, 6, 2472-2477.
  • Pingree, L.S.C.; Russell, M.T.; Marks, T.J.; Hersam, M.C. Monitoring Interface Traps in Operating Organic Light-Emitting Diodes Using Impedance Spectroscopy, Thin Solid Films, 2007, 515, 4783-4787.
  • Pingree, L.S.C.; Russell, M.T.; Marks, T.J.; Hersam, M.C. Field Dependent Negative Capacitance in Small-Molecule Organic Light-Emitting Diodes, J. Appl. Phys., 2006, 100, 044502-1-10.
  • Russell, M.T.; Pingree, L.S.C; Hersam, M.C.; Marks, T.J. Micro-Scale Features and Surface Chemical Functionality Patterned by Electron Beam Lithography. A Novel Route to Poly(dimethylsiloxane) (PDMS) Stamp Fabrication, Langmuir, 2006, 22, 6712-6718.
  • Facchetti, A.; Beverina, L.; van der Boom, M.E.; Shukla, A.; Dutta, P.; Evmenenko, G.; Marks, T.J.; Pagani, G.A. Pyrrole-Pyridine-Based Multibranched Dyes. The Influence of Dibranched Chromophore Architecture on Covalent Self-Assembly, Thin-Film Microstructure, and Optical and Electro-Optic Response, J. Am. Chem. Soc., in press.
  • Kang, H.; Facchetti, A.; Jiang, H.; Zhu, P.; Marks, T.J. Synthesis and Unprecedented Electro-Optic Response Properties of Twisted p-System Chromophores, MRS Symposium Proceedings, 2005, 883, 151-156.
  • Kang, H.; Facchetti, A.; Stern, C.L.; Rheingold, A.L.; Marks, T.J. Efficient Synthesis and Structural Characteristics of Zwitterionic Twisted Pi-Electron System Biaryls, Organic Letters, 2005, 7, 3721-3724.
  • Kang, H.; Facchetti, A.; Zhu, P.; Jiang, H.; Yang, Y.; Cariati, E.; Righetto, S.; Ugo, R.; Liu, Z.; Ho, S.-T.; Marks, T.J. Exceptional Molecular Hyperpolarizabilities in Twisted p–System Chromophores, Angew. Chem. Int. Ed. Engl, 2005, 44, 7922-7925.
  • Huang, Q.; Evmenenko, G.A.; Dutta, P.; Lee, P.; Armstrong, N.R.; Marks, T.J. Covalently Bound Hole-Injecting Nanostructures. Systematics of Molecular Architecture, Thickness, Saturation, and Electron-Blocking Characteristics on Organic Light-Emitting Diode Luminance, Turn-on Voltage, and Quantum Efficiency, J. Am. Chem. Soc., 2005, 127, 10227-10242.
  • Huang, Q.; Evmenenko, G.A.; Li, J.; Dutta, P.; Marks, T.J. Triarylamine Siloxane Anode Functionalization/Hole Injection Layers in High Efficiency/High Luminance Small-Molecule Green-and Blue-Emitting Organic Light-Emitting Diodes.  A Systematic Investigation, J. Appl. Phys., 2007, 101, 093101.
  • Huang, Q.; Li, J.; Evmenenko, G.A.; Dutta, P.; Marks, T.J. Nanoscale “Engineered” Anode Adsorbates for Probing OLED Interfacial Structure-Charge Injection/Luminance Relationships. Large, Structure-Dependent Effects, Chem. Mater., in press.
  • Huang, Q.; Evmenenko, G.A.; Dutta, P.; Lee, P.; Armstrong, N.R.; Marks, T.J. Nanoscale Hole Transport Layer Constituents Having Covalent Binding to Indium Tin Oxide Anodes. New Approach to Hole Transporting Materials for Organic Light-Emitting Diodes, J. Am. Chem. Soc., in press.
  • Ho, S.-T.; Liu, Z.; Ma, J.; Xu, G.; Liu, B.; Marks, T.J.; Zhu, P.; Kang, H.; Facchetti, A. Self-Assembled Materials Systems and Devices for R-FLICS, Proc. GOMACTech-04, 2005, 231-234.
  • Yan, H.; Lee, P.; Graham, A.; Armstrong, N.R.; Evmenenko, G.A.; Dutta, P.; Marks, T.J. High-Performance Hole Transport Layers for Polymer Light-Emitting Diodes.  Implementation of Organosiloxane Crosslinking Chemistry in Polymeric Electroluminescent Devices, J. Am. Chem. Soc., 2005, 127, 3172-3183.
  • Li, Q.; Kumar, V.; Li, Y.; Zhang, H.; Marks, T.J.; Chang, R.P.H. Fabrication of ZnO Nanorods and Nanotubes in Aqueous Solutions, Chem. Mater., in press.
  • Kang, H.; Zhu, P.; Yang, Y.; Facchetti, A.; Marks. T.J. Self-Assembled Electro-Optic Thin Films with Dramatically Blue-Shifted Optical Absorption Based on a Novel X-Shaped Chromophore, J. Am. Chem. Soc., 2004, 126, 15974-15975.
  • Yan, H.; Marks, T.J. Electron-Blocking Mechanisms at the Hole Transport Layer-Emissive Layer Interface in Polymer Light-Emitting Diodes. Enhanced Device Performance with a Novel Electron- Blocking Interlayer, SPIE Sympos. Proc, 2004, 5519, 270-279.
  • Pingree, L.S.C.; Scott, B.J.; Russell, M.T.; Marks, T.J.; Hersam, M.C. Frequency Dependent Negative Capacitance in Organic Light-Emitting Diodes, Appl. Phys. Lett., 2005, 86, 073509.
  • Zhu, P.; Kang, H.; van der Boom, M.E.; Liu, Z.; Xu, G.; Ma, J.; Zhou, D.; Ho, S.-T.; Marks, T.J. Self-Assembled Materials and Devices that Process Light, SPIE Sympos. Proc., 2004, 5621, 105-116.
  • Facchetti, A.; Annoni, E.; Beverina, L.; Morone, M.; Zhu, P.; Marks, T.J.; Pagani, G.A. Very Large Electro-Optic Responses in H-Bonded Heteroaromatic Films Grown by Physical Vapor Deposition, Nature Materials, 2004, 3, 910-917.
  • Kang, Hu; Zhu, Peiwang; Yang, Yu; Evmenenko, Guennadi; Dutta, Pulak; Marks, Tobin J. Self-assembled electro-optic thin films with dramatically blue-shifted optical absorption based on novel X-shaped two-dimensional charge-transfer chromophores. Polymeric Materials: Science and Engineering, 2004, 91, 267-268.
  • Yan, H.; Scott, B.J.; Kern, M.M.; Huang, Q.; Marks, T.J. Enhanced Polymer Light-Emitting Diode Performance Using a Crosslinked Network Electron-Blocking Interlayer, Advan. Mater., 2004, 16, 1948-1953.
  • Yan, H.; Huang, Q.; Scott, B.J.; Marks, T.J. A Polymer Blend Approach to Fabricating the Hole Transport Layer for Polymer Light-Emitting Diodes, Appl. Phys. Lett., 2004, 84, 3873-3875.
  • Pingree, L.S.C.; Hersam, M.C.; Kern, M.M.; Scott, B.J.; Marks, T.J. Spatially Resolved Electroluminesence Via Conductive Atomic Force Microscopy Techniques, Appl. Phys. Lett., 2004, 85, 344-346.
  • Veinot, J.G.C.; Marks, T.J. Toward the Ideal Organic Light-Emitting Diode: The Versatility and Utility of Interfacial Tailoring by Siloxane Self-Assembly, Accts. Chem. Res., in press.
  • Yang, Y.; Huang, Q.; Metz, A.W.; Ni, J.; Jin, S.; Marks, T.J.; Madsen, M.E.; DiVenere, A.; Ho, S.-T. High Performance Organic Light-Emitting Diodes Using ITO Anodes Grown on Plastic by Room Temperature Ion-Assisted Deposition, Adv. Mater., 2004, 16, 321-324.
  • Zhu, P.; Kang, H.; Facchetti, A.; Evmenenko, G.; Dutta, P.; Marks, T.J. Electro-Optic Thin Films Self-Assembled via Multiple Hydrogen Bonds from the Vapor Phase, Polymeric. Mat.: Sci & Eng., 2003, 89, 265-266.
  • Sun, D.-G.; Liu, Z.; Ma, J.; Xiao, Y.; Ho, S.-T.; Kang, H.; Zhu, P.; Marks, T.J. Loss Minimizing Strategies for Self-Assembled Superlattice Waveguiding Electro-Optic Modulators, SCI 2003 Proc., 2003, X, 76-80.
  • Huang, Q.; Evmenenko, G.; Dutta, P.; Marks, T.J. Molecularly “Engineered” Anode Adsorbates for Probing OLED Interfacial Structure-Charge Injection/Luminence Relationships. Large, Structure-Dependent Effects, J. Am. Chem. Soc., 2003, 125, 14704-14705.
  • Zhu, P.; Kang, H.; Facchetti, A.; Evmenenko, G.; Dutta, P.; Marks, T.J. Vapor Phase Self-Assembly of Electro-Optic Thin Films via Directed Triple Hydrogen Bonds, J. Am. Chem. Soc., 2003, 125, 11496-11497.
  • Keinan, S.; Zhu, P.; Ratner, M.A.; Marks, T.J. Self-Assembled Electro-Optic Superlattices. A Theoretical Study of Multilayer Formation and Response Using Donor-Acceptor, Hydrogen-Bond Building Blocks, Chem. Mater., 2004, 16, 1848-1854.
  • van der Boom, M.E.; Evmenenko, G.; Yu, C.; Dutta, P.; Marks, T.J. Interrupted-Growth Studies of the Self-Assembly of Intrinsically Acentric Siloxane-Based Monolayers, Langmuir, 2003, 19, 10531-10537.
  • Marks, T.J.; Ho, S.-T.; Liu, Z.; Zhu, P.; Sun, D.-G.; Ma, J.; Xiao, Y.; Kang H. Electro-Optic Waveguide Modulators by the Integration of Self-Assembled Superlattices with Polymeric and Semiconductor Materials, SPIE Proc., 2003, 4991, 133-143.
  • Zhao, Y.-G.; Chang, S.; Wu, A.; Lu, H.-L.; Ho, S.T.; van der Boom, M.E.; Marks, T.J. Second-Generation Approach to All-Organic Modulators Based on Intrinsically Polar Self-Assembled Molecular Superlattices, Optical Engineering Letters, 2003, 42, 298-299.
  • Keinan, S.; Zojer, E.; Brédas, J.-L.; Ratner, M.A.; Marks, T.J. Twisted p-System Electro-Optic Chromophores. A CIS vs. MRD-CI Theoretical Investigation, THEOCHEM, 2003, 633, 227-235.
  • Yan, H.; Huang, Q.; Cui, J.; Veinot, J.G.C.; Kern, M.; Marks, T.J. Enhancing the Performance of Blue Light-Emitting Polymer Diodes via Anode Modification Using a Self-Assembled Monolayer, Advan. Mater., 2003, 15, 835-838.
  • Facchetti, A.; Abbotto, A.; Beverina, L.; van der Boom, M.E.; Dutta, P.; Evmenenko, G.; Pagani, G.A.; Marks, T.J. Layer-by-Layer Self-Assembled Pyrrole-Based Donor-Acceptor Chromophores as Electro-Optic Materials, Chem. Mater., 2003, 15, 33-38.
  • Huang, Q.; Cui, J.; Veinot, J.G.C.; Yan, H.; Marks, T.J. Realization of High Efficiency/High Luminance Small Molecule Organic Light-Emitting Diodes. Synergistic Effects of Siloxane Anode Functionalization/Hole Injection Layers and Hole-, Exciton- Blocking/Electron Transport Layers, Appl. Phys. Lett., 2003, 82, 331-333.
  • Koide, Y.; Such, M.W.; Basu, R.; Evmenenko, G.; Cui, J.; Dutta, P.; Hersam, M.C.; Marks, T.J. Hot Microcontact Printing for Patterning ITO Surfaces. Methodology, Morphology, Microstructure, and OLED Charge Injection Barrier Imaging, Langmuir, 2003, 19, 86-93.
  • Huang, Q.; Kang, H.; Veinot, J.; Yan, H.; Zhu, P.; Marks, T.J. Nanoprecise Self-Assembly of Electro-Optic and Electroluminescent Molecular Arrays, In Organic Nanophotonics, Agranovich, V.; Charra, F.; Kajzar, F., Eds., Kluwer Publishers, Dordrecht Holland, 2003, pp. 241-263.
  • Cui, J.; Huang, Q.; Veinot, J.C.G.; Yan, H.; Wang, Q.; Hutchison, G.R.; Richter, A.G.; Evmenenko, G.; Dutta, P.; Marks, T.J. Anode Interfacial Engineering Approaches to Enhancing Anode/Hole Transport Layer Interfacial Stability and Charge Injection Efficiency in Organic Light-Emitting Diodes, Langmuir, 2002, 18, 9958-9970.
  • Zhu, P.; van der Boom, M.E.; Kang, H.; Evmenenko, G.; Dutta, P.; Marks, T.J. Realization of Rapid Layer-by-Layer Siloxane-Based Self-Assembly as an Efficient Route to Structurally Regular Acentric Superlattices with Large Electro-Optic Responses, Chem. Mater., 2002, 14, 4982-4989.
  • Marks, T.J.; Veinot, J.G.C.; Cui, J.; Yan, H.; Wang, A.; Edleman, N.L.; Huang, Q.; Lee, P.; Armstrong, N.R. Progress in High Work Function TCO OLED Anode Alternatives and OLED Nanopixelation, Synthetic Metals, 2002, 127, 29-35.
  • Huang, Q.; Cui, J.; Yan, H.; Veinot, J.G.C.; Marks, T.J. Small Molecule Organic Light-Emitting Diodes Can Exhibit High Performance Without Conventional Hole Transport Layers, Appl. Phys. Lett., 2002, 81, 3528-3530.
  • Wang, G.; Zhu, P.; Marks, T.J.; Ketterson, J.B. Ultra-Fast Frequency-Selective Optical Switching Based on Thin Self-Assembled Organic Chromophoric Films with a Large Second-Order Nonlinear Response, Appl. Phys. Lett., 2002, 81, 2169-2171.
  • Facchetti, A.; Abbotto, A.; Beverina, L.; van der Boom, M.E.; Dutta, P.; Evmenenko, G.; Marks, T.J., Pagani, G.A. Azinium-( pi-Bridge)-Pyrrole NLO-Phores: Influence of Heterocycle Acceptors on Chromophoric and Self-Assembled Thin-Film Properties, Chem. Mater. 2002, 14, 4996-5005.
  • Cui, J.; Huang, Q.; Veinot, J.G.C.; Yan, H.; Marks, T.J. Mechanisms of Organic Light-Emitting Diode Hole Injection Enhancement. Microstructure-Function in Silane-Derivatized Hole Injection/Adhesion and Copper Phthalocyanine Interlayers, Advanced Materials, 2002, 14, 565-569
  • van der Boom, M.E.; Zhu, P.; Evmenenko, G.; Malinsky, J.E.; Lin, W.; Dutta, P.; Marks, T.J. Nanoscale Consecutive Self-Assembly of Thin-Film Molecular Materials for Electrooptic Switching. Chemical Streamlining and Ultrahigh Response Chromophores, Langmuir, 2002, 18, 3704-3707.
  • Malinsky, J.E.; Veinot, J.G.C.; Jabbour, G.E.; Shaheen, S.E.; Anderson, J.D.; Lee, P.; Richter, A.G.; Burin, A.L.; Ratner, M.A.; Marks, T.J.; Armstrong, N.R.; Kippelen, B.; Dutta, P.; Peyghambarian, N. Nanometer-Scale Dielectric Self-Assembly Process for Anode Modification in Organic Light-Emitting Diodes. Consequences for Charge Injection and Enhanced Luminous Efficiency, Chem. Mater., 2002, 14, 3054-3065.
  • Veinot, J.G.C.; Yan, H.; Smith, S.M.; Cui, J.; Huang, Q.; Marks, T.J. Fabrication and Properties of Organic Light-Emitting "Nanodiode" Arrays, Nano Letters, 2002, 2, 333-335.
  • Facchetti, A.; van der Boom, M.E.; Abbotto, A.; Beverina, L.; Marks, T.J.; Pagani, G.A. Design and Preparation of Zwitterionic Organic Thin Films: Self-Assembled Siloxane-Based, Thiophene-Spaced N-Benzylpyridinium Dicyanomethanides as Nonlinear Optical Materials, Langmuir, 2001, 17, 5939-5942.
  • Evmenenko, G.; Dugan, S.W.; Kmetko, J.; Dutta, P.; van der Boom, M.E.; Marks, T.J. Specular X-Ray Reflectivity Study of Ordering in Self-Assembled Organic-Inorganic Electro-Optic Multilayer Films, J. Chem. Phys., 2001, 115, 6722-6727.
  • Zhao, Y.-G.; Wu, A.; Lu, H.-L.; Chang, S.; Lu, W.-K.; Ho, S.T.; van der Boom, M.E.; Marks, T.J. Traveling Wave Electro-Optic Phase Modulators Based on Intrinsically Polar Self-Assembled Chromophoric Superlattices, Appl. Phys. Lett., 2001, 79, 587-589.
  • van der Boom, M.E.; Evmenenko, G.; Dutta, P.; Marks, T.J. Nanoscale Refractive Index Tuning of Siloxane-Based Self-Assembled Electro-Optic Superlattices, Advanced Functional Materials, 2001, 11, 393-397.
  • Yan, M.; Koide, Y.; Marks, T.J.; Chang, R.P.H. Selective Area Atomic Layer Epitaxy. Growth of ZnO Features on Microcontact Patterned Substrates, Appl. Phys. Lett., 2001, 79, 1709-1711.
  • Cui, J.; Wang, A.; Edleman, N.L.; Lee, P.; Armstrong, N.R.; Marks, T.J. ITO Alternatives. High Work Function Transparent Conducting Oxides as Improved Anodes for Organic Light-Emitting Diodes, Advanced Materials, 2001, 13, 1476-1480.
  • Pati, S.K.; Marks, T.J.; Ratner, M.A. Optical Limiters. Conformationally Tuned Large Two-Photon Absorption Cross-Sections in Simple Molecular Chromophores, J. Am. Chem. Soc., 2001, 123, 7287-7291.
  • Cui, J.; Huang, Q.; Wang, Q.; Marks, T.J. Nanoscale Covalent Self-Assembly Approach to Enhancing Anode-Hole Transport Layer Interfacial Stability and Charge Injection Efficiency in Organic Light-Emitting Diodes, Langmuir, 2001, 17, 2051-2054.
  • Koide, Y.; Wang, Q.; Cui, J.; Benson, D.D.; Marks, T.J. Patterned Luminescence of Organic Light-Emiting Diodes by Hot Microcontact Printing of Self-Assembled Monolayers, J. Amer. Chem. Soc., 2000, 122, 11266-11267.
  • van der Boom, M.; Richter, A.G.; Malinsky, J.E.; Lee, P.A.; Armstrong, N.R.; Dutta, P.; Marks, T.J. Single Reactor Route to Polar Superlattices. Layer-by-Layer Self-Assembly of Large Response Molecular Electro-Optic Materials by a Protection-Deprotection Strategy, Chem. Mater., 2001, 13, 15-17.
  • Zhao, Y.G.; Lu, W.-K.; Ma, Y.; Kim, S.-S.; Ho, S.T.; Marks, T.J. Novel Polymer Waveguides Useful Over a Very Wide Wavelength Range From the Ultraviolet to Infrared, Appl. Phys. Lett., 2000, 77, 2961-2963.
  • Cui, J.; Wang, Q.; Marks, T.J. Covalent Self-Assembly Approach to Improvement of Interfacial OLED Anode/Hole Transport Layer Contacts, Polymer Mater. Sci. Eng. 2000, 83, 239-240.
  • Koide, Y.; Marks, T.J. High Resolution Organic Light-Emitting Diode (OLED) Pixels Fabricated by High-Temperature Microcontact Printing, Polymer Mat. Sci. Eng., 2000, 83, 212.
  • van der Boom, M.E.; Richter, A.G.; Malinsky, J.E.; Dutta, P.; Marks, T.J. Layer-by-Layer Self-Assembly of Large Response Molecular Electro-Optic Materials by a Desilylation Strategy, Polymer Mat. Sci. Eng., 2000, 83, 160.
  • Davey, M.H.; Lee, V.Y.; Wu, L.-M.; Moylan, C.R.; Volksen, W.; Knoesen, A.; Miller, R.D.; Marks, T.J. High Temperature Polymers for Second-Order Nonlinear Optics. Synthesis and Properties of Chromophore-Embedded Polyimides, Chem. Mater., 2000, 12, 1679-1693.
  • Albert, I.D.L.; Marks, T.J.; Ratner, M.A.; Rauh, R.D. Chromophores for Optical Limiting. Correlation Effects on the Triplet-Triplet Absorption Energies of Organic Molecules, J. Phys. Chem. B., 2000, 104, 837-844.
  • Marks, T.J.; Cui, J.; Malinsky, J.E.; Wang, Q.; Jabbour, G.E.; Shaheen, S.E.; Anderson, J.D.; Lee, P.A.; Richter, A.G.; Kippelen, B.; Dutta, P.; Peyghambarian, N.; Armstrong, N.R. Approaches to Organic Light-Emitters Via Layer-By-Layer Self-Assembly, Polym. Prepr., 1999, 40, 1196-1197.
  • Davey, M.H.; Lee, V.Y.; Miller, R.D; Marks, T.J. Synthesis of Aryl Nitroso Derivatives by tert-Butyl Hypochlorite Oxidation in Homogeneous Media. Intermediates for the Preparation of High-Hyperpolarizability Chromophore Skeletons, J. Org. Chem., 1999, 64, 4976.
  • Li, W.; Wang, Q.; Shaheen S.E.; Chou, H.; Jabbour, G.E.; Anderson, J.; Lele, P.; Cui, J.; Kippelen, B.; Peyghambarian, N.; Armstrong, N.R.; Marks, T.J. Spin-Coating Processes for Covalently Interlocked Light-Emitting Device Structures, Advanced Materials, 1999, 11, 730-734.
  • Wang, Q.; Li, W.; Jabbour, G.E.; Cui, J.; Marks, T.J.; Kippelen, B.; Peyghambarian, N. Micro-Contact Printing Approaches to Organic Light-Emitting Diode Pixels, Polym. Prepr., 1999, 40, 1248.
  • Malinsky, J.E.; Marks, T.J.; Jabbour, G.E.; Shaheen, S.E.; Anderson, J.D.; Richter, A.G.; Armstrong, N.R.; Kippelen, B.; Dutta, P.; and Peyghambarian, N. Self-Assembly Processes for Organic LED Electrode Passivation and Charge Injection Balance, Advan. Mater., 1999, 11, 227.
  • Albert, I.D.L.; Marks, T.J.; Ratner, M.A. Large Molecular Hyperpolarizabilities In Push-Pull Porphyrins. Molecular Planarity and Auxilliary Donor and Acceptor Effects, Chem. Mater. 1998, 10, 753.
  • Albert, I.D.L.; Marks, T.J.; Ratner, M.A. First Hyperpolarizability of Molecular Chromophores: Practical Computational Approaches, in Progress in Organic Nonlinear Optics, Kuzyk, M.; Dirk, C.R. eds., Marcel Dekker: NY, 1998, pp. 37-109.
  • Li, W.; Malinsky, J.E.; Chou, H.; Ma, W.; Geng, L.; Marks, T.J.; Jabbour, G.E.; Shaheen, S.E.; Kippelen, B.; Peyghambarian, N.; Armstrong, N. Molecular Self-Assembly Routes to Optically Functional Thin Films: Electroluminescent Multilayer Structures, MRS Sympos. Proc., 1998, 488, 385.
  • Malinsky, J.E.; Li, W.; Chou, H.; Ma, W.; Geng, L.; Marks, T.J.; Jabbour, G.E.; Shaheen, S.E.; Kippelen, B.; Peyghambarian, N.; Dutta, P.; Richter, A.J.; Armstrong, N.R.; Anderson, J.L. Molecular Self-Assembly Approaches to Multilayer Organic Light-Emitting Diode Structures, SPIE Proc. 1998, 3281, 148.
  • Albert, I.D.L.; Marks, T.J.; Ratner, M.A. Remarkable NLO Response and Infrared Absorption In Simple Twisted Molecular -Chromophores, J. Am. Chem. Soc., 1998, 120, 11174.
  • Li, W.; Malinsky, J.E.; Chou, H.; Ma, W.; Geng, L.; Marks, T.J.; Jabbour, G.E.; Shaheen, S.E.; Kippelen, B; Peyghambarian, N.; Dutta, P.; Richter, G.; Armstrong, N.R.; Lee, P.A.; Anderson, J.D. Molecular Self-Assembly Routes to Electroluminescent Multilayer Structures, Polym. Prepr., 1998, 39, 1083.
 

C-Team

  • Cortes, N.E.S.; Liu, J.; Chen, C.; Marks, T.J.; Hersam, M.C. Nanoscale Writing of Transparent Conducting Oxides Features with a Focused Ion Beam, submitted for publication.
  • McCain, M.N.; He, B.; Sanati, J.; Wang, Q.J.; Marks, T.J. Aerosol-Assisted Chemical Vapor Deposition of Lubricating MoS2 Films.  Ferrous Substrates and Titanium Film Doping, Chem. Mater., in press.
  • Sheets, W.C.; Stampler, E.S.; Kabbour, H.; Bertoni, M.I.; Cario, L.; Mason, T.O.; Marks, T.J.; Poeppelmeier, K.R. Facile Synthesis of BiCuOS by Hydrothermal Methods, Inorg. Chem., 2007, 46, 10741-10748.
  • Jin, S.; Yang, Y.; Medvedeva, J.E.; Wang, L.; Li, S.; Cortes, N.; Metz, A.W.; Ni, J.; Hersam, M.C.; Freeman, A.J.; Marks, T.J. Tuning the Properties of Transparent Oxide Conductors.  Dopant Ion Size and Electronic Structure Effects on CdO-Based Transparent Conductive Oxides.  Ga- and In – Doped CdO Thin Films Grown by MOCVD, Chem. Mater., 2008, 20, 220-230.
  • Tezuka, K.; Sheets, W.C.; Kurihara, R.; Shan, Y.J.; Imoto, H.; Marks, T.J.; Poeppelmeier, K.R. Synthesis of Covellite (CuS) from the Elements, Solid State Sciences, 2007, 9, 95-99.
  • McCain, M.N.; Schneider, S.; Salata, M.R.; Marks, T.J. Silver Phosphinoborate Complexes as Precursors for Metallic Silver Deposition, Inorg. Chem., in press.
  • Meier, A.; Desai, A.; Wang, L.; Marks, T.; Wessels, B.; Phase Stability of Heteroepitaxial Polydomain BaTiO3 Thin Films, J. Materials Research, 2007, 22, 1384-1389.
  • Schneider, S.; Dzudza, A.; Raudaschl-Sieber, G.; Marks, T.J. Copper(I) tert-Butylthiolato Clusters as Single-Source Precursors for High-Quality Chalcocite Thin Films:  Precursor Chemistry in Solution and the Solid State, Chem. Mater., 2007, 19, 2780-2785.
  • Schneider, S.; Ireland, J.R.; Hersam, M.C.; Marks, T.J. Copper(I) tert-Butylthiolato Clusters as Single-Source Precursors for High-Quality Chalcocite Thin Films:  Film Growth and Microstructure Control, Chem. Mater., 2007, 19, 2768-2779.
  • Sheets, W.C.; Stampler, E.S.; Bertoni, M.I.; Sasaki, M.; Marks, T.J.; Mason, T.O.; Poeppelmeier, K.R. Silver Delafossite Oxides,Inorg. Chem., 2008,47, 2696-2705.
  • Yang, Y.; Wang, L.; Yan, H.; Jin, S.; Marks, T.J. Highly Transparent and Conductive Double-Layer Thin Films as Anodes for Organic Light-Emitting Diodes, Appl. Phys. Lett., 2006, 89, 051116-1-3.
  • Schneider, S.; Roberts, J.A.S.; Salata, M.R.; Marks, T.J. Mixed Diketonate Thiolate Copper(I) Precursors for Cu2S: Control of Thermal Reaction Pathways By Lewis Acid and Base Cluster Building Blocks, Angew. Chem. Int. Ed., in press.
  • Xu, G.; Ma, J.; Liu, Z.; Liu, B.; Ho, S.-T.; Zhu, P.; Wang, L.; Yang, Y.; Marks, T.J.; Luo, J.; Tucker, N.; Jen. A.K.-Y. Low-Voltage Organic Electro-Optic Modulators Using Transparent Conducting Oxides as Electrodes, Optics Express, 2005, 13, 7380-7385.
  • Schneider, S.; Yang, Y.; Marks, T.J. Growth of Highly Oriented Chalcocite Thin Films on Glass By Aerosol-Assisted Spray Pyrolysis Using a New Single-Source Copper Thiolate Precursor, Chem. Mater., 2005, 17, 4286-4288.
  • Wang, L.; Yang, Y., Ni, J.; Stern, C.L.; Marks, T.J. Synthesis and Characterization of Low-Melting, Highly Volatile Magnesium MOCVD Precursors and Their Implementation in MgO Thin Film Growth, Chem. Mater., 2005, 17, 5697-5704.
  • Wang, L.; Yang, Y.; Marks, T.J. Near-Infrared Transparent Electrodes for precision Teng-Man Electro-Optic Measurements. In2O3 Thin Film Electrodes with Tunable Near-Infrared Transparency, Appl. Phys. Lett., 2005, 87, 161107/1-161107/3.
  • Yang, Y.; Jin, S.; Medvedeva, J.E.; Ireland, J.R.; Metz, A.W.; Ni, J.; Hersam, M.C.; Freeman, A.J.; Marks, T.J. CdO as the Archetypical Transparent Conducing Oxide. Dopant Ionic Radius and Electronic Structure Effects on Charge Transport Characteristics and Band Structure, J. Am. Chem. Soc., 2005, 127, 8796-8804.
  • McCain, M.N.; Metz, A.W.; Yang, Y.; Stern, C.L.; Marks, T.J. Bis[di(2,2,2-trifluoroethyl)dithiocarbamato]Cu (II). A Volatile Precursor for the Efficient Growth of Cuprous Sulfide Films by MOCVD, CVD, 2005, 11, 291-294.
  • Yang, Y.; Jin, S.; Medvedeva, J.E.; Ireland, J.R.; Metz, A.W.; Ni, J.; Hersam, M.C.; Freeman, A.J.; Marks, T.J. CdO as the Archetypical Transparent Conducing Oxide. Dopant Ionic Radius and Electronic Structure Effects on Charge Transport Characteristics and Band Structure, J. Am. Chem. Soc., in press.
  • Ni, J.; Wang, L.; Marks, T.J. Charge Transport and Optical Properties of MOCVD Grown Mg-and Tin-Doped In2O3 Transparent Conducting Oxide Thin Films, Inorg. Chem., in press.
  • Yang, Y.; Huang, Q.; Jin, S.; Metz, A.W.; Ni, J.; Marks, T.J. Highly Transparent and Conductive CdO Thin Films as Anodes for Organic Light-Emitting Diodes, Information Display, Special Issue on OLEDs, J. Soc. Info. Disp., 2005, 13, 383-387.
  • Ni, J.; Yan, H.; Wang, A.; Yang, Y.; Stern, C.L.; Metz, A.W.; Jin, S.; Wang, L.; Marks, T.J.; Ireland, J.; Kannewurf, C.R. Synthesis and Characterization of Volatile Zinc MOCVD Precursors and Their Implementation in Growth of Highly Transparent, Conducting Zinc- and Tin-Doped Indium Oxide Anodes for Polymer Light-Emitting Diodes, J. Am. Chem. Soc., 2005, 127, 5613-5624.
  • Metz, A.W.; Lane, M.A.; Kannewurf, C.R.; Poeppelmeier, K.R.; Marks, T.J. MOCVD Growth of Transparent Conducting Cd2SnO4 Thin Films, Adv. Mater. CVD, 2004, 10, 297-300.
  • Metz, A.W.; Ireland, J.R.; Zheng, J.-G.; Lobo, R.P.S.M.; Yang, Y.; Ni, J.; Stern, C.L.; Dravid, V.P.; Bontemps, N.; Kannewurf, C.R.; Poeppelmeier, K.R.; Marks, T.J. Transparent Conducting Oxides. Texture and Microstructure Effects on Charge Carrier Mobility in MOCVD-Derived CdO Thin Films Grown with a Thermally Stable, Low-Melting Precursor, J. Am. Chem. Soc., 2004, 126, 8477-8492.
  • Jin, S.; Yang, Y.; Ireland, J.R.; Medvedeva, J.E.; Metz, A.W.; Ni, J.; Freeman, A.J.; Kannewurf, C.R.; Marks, T.J. Dopant Ion Size and Electronic Structure Effects on Transparent Conducting Oxides.  Sc-Doped CdO Thin Films Grown by MOCVD, J. Am. Chem. Soc., 2004, 126, 13787-13793.
  • Towner, D.J.; Ni, J.; Marks, T.J.; Wessels, B.W. Effects of Two-Stage Deposition on the Structure and Properties of Heteroepitaxial BaTiO3 Thin Films, J. Crystal Growth, 2003, 255, 107.
  • Wang, A.; Edleman, N.L.; Babcock, J.R.; Marks, T.J.; Lane, M.A.; Brazis, P.R.; Kannewurf, C.R. Growth, Microstructure, Charge Transport, and Transparency of Random Polycrystalline and Heteroepitaxial Metalorganic Chemical Vapor Deposition- Derived Gallium-Indium-Oxide Thin Films, J. Mater. Res., 2002, 17, 3155-3162.
  • Edleman, N.L.; Belot, J.A.; Metz, A.W.; Babcock, J.R.; Kawaoka, A.M.; Ni, J.; Metz, M.V.; Flschenriem, C.J.; Stern, C.L.; Liable-Sands, L.M.; Rheingold, A.L.; Markworth, P.R.; Chang, R.P.H.; Chudzik, M.P.; Kannewurf, C.R.; Marks, T.J. Synthesis and Characterization of Volatile, Fluorine-Free β-Ketoiminate Lanthanide MOCVD Precursors and Their Implementation in Low Temperature Growth of Epitaxial CeO2 Buffer Layers for Superconducting Electronics, Inorg. Chem., 2002, 41, 5005-5023.
  • Asahi, R.; Wang, A.; Babcock, J.R.; Edleman, N.L.; Metz, A.W.; Lane, M.A.; Dravid, V.P.; Kannewurf, C.R.; Freeman, A.J.; Marks, T.J. First-Principles Calculations for Understanding High Conductivity and Optical Transparency in In­xCd1-xO Films, Thin Solid Films, 2002, 411, 101-105.
  • Asahi, R.; Babcock, J.R.; Edleman, N.L.; Kammler, D.R.; Ko, D.; Lane, M.A.; Metz, A.W.; Wang, A.; Yan, M.; Chang, R.P.H.; Dravid, V.; Freeman, A.J.; Kannewurf, C.R.; Marks, T.J.; Mason, T.O.; Poeppelmeier, K.R. New Transparent Conducting Oxides. Progress in Understanding Cadium-Containing Bulk and Thin-Film Materials, in Kapur, V.K.; McConnell, R.D.; Carlson, D.; Caesar, G.P.; Rohatgi, A.; Smith, J., Eds. "hotovoltaics for the 21st Century," Electrochemical Society:  Washington, D.C., 2001, pp. 333-348.
  • Markworth, P.R.; Liu, X.; Dai, J.; Fan, W.; Chang, R.P.H.; Marks, T.J. Coherent Islanding of Cu2O Films Grown by Metal-Organic Chemical Vapor Deposition on MgO(110), J. Mater. Res., 2001, 3, 3091-3094.
  • Wang, A.; Babcock, J.R.; Edleman, N.L.; Metz, A.W.; Lane, M.A.; Asahi, R.; Dravid, V.P.; Kannewurf, C.R.; Freeman, A.J.; Marks, T.J. Indium-Cadmium-Oxide Films Having Exceptional Electrical Conductivity and Optical Transparency. Clues for Optimizing Transparent Conductors, Proc. Nat. Acad. Sci., 2001, 98, 7113-7116.
  • Fan, W.; Markworth, P.R.; Marks, T.J.; Chang, R.P.H. Growth of Atomically Flat Homoepitaxial Magnesium Oxide Thin Films By Metal-Organic Chemical Vapor Deposition, Materials Chemistry and Physics, 2001, 70, 191-196.
  • Babcock, J.R.; Wang, A.; Metz, A.W.; Edleman, N.L.; Metz, M.V.; Lane, M.A.; Kannewurf, C.R.; Marks, T.J. Transparent Conducting CdO Thin Film Growth Using a Highly Volatile, Thermally and Air-Stable Cadmium Precursor, Advanced Materials CVD, 2001, 7, 239-242.
  • Freeman, A.J.; Poeppelmeier, K.R.; Mason, T.O.; Chang, R.P.H.; Marks, T.J. Chemical and Thin Film Strategies for new Transparent Conducting Oxides, Mats. Res. Soc. Bull., 2000, 25, 45-51.
  • Babcock, J.R.; Liu, X.; Ott, A.W.; Lane, M.A.; Belot, J.A.; Metz, M.V.; Chang, R.P.H.; Marks, T.J., Kannewurf, C.R. Plasma-Assisted MOCVD Growth of Superconducting NbN Thin Films Using Nb Dialkylamide and Nb Alkylimide Precursors, Advanced Materials CVD, 2001, 7, 25-28.
  • Babcock, J.R.; Benson, D.D.; Wang, A.; Edleman, N.L.; Belot, J.A.; Metz, M.V.; Marks, T.J. Polydentate Amines as CVD Precursor Ancillary Ligands. Epitaxial MgO Thin Film Growth Using a Highly Volatile, Thermally- and Air-Stable Magnesium Precursor, Advanced Materials, CVD, 2000, 6, 180-183.
  • Teren, A.R.; Belot, J.A.; Edleman, N.L.; Marks, T.J.; Wessels, B.W. Metal-Organic Chemical Vapor Deposition of Epitaxial BaTiO3 Films Using a Liquid Barium Precursor, Advanced Materials, CVD, 2000, 6, 175-177.
  • Wang, A.; Edleman, N.L.; Babcock, J.R.; Marks, T.J.; Lane, M.A.; Brazis, P.; Kannewurf, C.R. Metal-Organic Chemical Vapor Deposition of In-Zn-Sn-O and In-Ga-Sn-O Transparent Conducting Oxide Thin Films, MRS Symposium Series, 2000, 607, 345-352.
  • Freeman, A.J.; Poeppelmeier, K.R.; Mason, T.O.; Chang, R.P.H.; Marks, T.J. Chemical and Thin Film Strategies for new Transparent Conducting Oxides, Mats. Res. Soc. Bull., 2000, 25, 45-51.
  • Babcock, J.R.; Benson, D.D.; Wang, A.; Edleman, N.L.; Belot, J.A.; Metz, M.V.; Marks, T.J. Polydentate Amines as CVD Precursor Ancillary Ligands. Epitaxial MgO Thin Film Growth Using a Highly Volatile, Thermally- and Air-Stable Magnesium Precursor, Adv. Mater., CVD, 2000, 6, 180-183.
  • Teren, A.R.; Belot, J.A.; Edleman, N.L.; Marks, T.J.; Wessels, B.W. Metal-Organic Chemical Vapor Deposition of Epitaxial BaTiO Films Using a Liquid Barium Precursor, Adv. Mater., CVD, 2000, 6, 175-177.
  • Studebaker, D.B.; Neumayer, D.A.; Hinds, B.J.; Stern, C.L.; Marks, T.J. Encapsulating Bis(-Ketoiminato) Polyethers. Volatile, Fluorine-Free Barium Precursors for Metal-Organic Chemical Vapor Deposition, Inorg. Chem., 2000, 39, 3148-3157.
  • McNeely, R.J.; Belot, J.A.; Marks, T.J.; Chudzik, M.P.; Rocci, M.A.; Kannewurf, C.R.; Wang, Y.; Dravid V.P. Phase-Selective Growth of MOCVD-Derived Tl1Ba2Ca2Cu3O9-x Thin Films via Thallium Fluoride Anneal. Phase Evolution, Microstructural Changes, and Charge Transport Characteristics, J. Mater. Res., 2000, 15, 1083-1097.
  • Wang, A.; Belot, J.A.; Marks , T.J. Film Microstructure - Deposition Condition Relationships in the Growth of Epitaxial NiO Films by MOCVD on Oxide and Metal Substrates, J. Mater. Res., 1999, 14, 1132-1134.
  • Belot, J.A.; McNeely, R.J.; Wang, A.; Reedy, C.J.; Marks, T.J.; Yap, G.; Rheingold, A.L. Expedient Route to Volatile Zirconium Metal-Organic Chemical Vapor Deposition Precursors Using Amide Synthons and Implementation in Yttria-Stabilized Zirconia Film Growth, J. Mater. Res., 1999, 14, 12-14.
  • Wang, A.; Belot, J.A.; Marks, T.J.; Markworth, P.R.; Chang, R.P.H.; Chudzik, M.P.; Kannewurf, C.R. Buffers for Coated Conductors. Low Temperature Growth of CeO2 Films by Metal Organic Chemical Vapor Deposition, Physica C, 1999, 320, 154.
  • Belot, J. A; Wang, A.; Marks, T.J.; McNeely, R. J.; Liable-Sands, L.; Rheingold, A. L. Liquid Lanthanides: Volatile, Low-Melting, Fluorine-Free Precursors for Metal-Organic Chemical Vapor Deposition of Thin Metal Oxide Films, Advan. Mater. (Chem. Vap. Depos.) 1999, 5, 65.
  • Studebaker, D.B.; Zhang, J.; Marks, T.J.; Wang, Y.Y.; Dravid, V.P.; Schindler, J.L.; Kannewurf, C.R. Liquid Source Metal-Organic Chemical-Vapor Deposition of High-Quality YBa2Cu3O7-X Films on Polycrystalline Silver Substrates, Appl. Phys. Lett. 1998, 72, 1253.
  • Chang, K.-W.; Wessels, B.W.; Qian, W.; Dravid, V.P.; Schindler, J.L.; Kannewurf, C.R.; Studebaker, D.B.; Marks, T.J.; Feenstra, R. In-situ Growth and Doping of Oxycarbonate Sr2CuO2(CO3) Epitaxial Thin Films, Physica C, 1998, 303, 11.
  • Wang, A.; Cheng, S.C.; Belot, J.A.; McNeely, R.J.; Cheng, J.; Marcordes, B.; Marks, T.J.; Dai, J.Y.; Chang, R.P.H.; Schindler, J.L.; Chudzik, M.P.; Kannewurf, C.R. Metal-Organic Chemical Vapor Deposition Routes to Films of Transparent Conducting Oxides, MRS Sympos. Proc., 1998, 495, 3.
  • Neumayer, D.A.; Belot, J.A.; Feezel, R.L.; Reedy, C.; Stern, C.L.; Marks, T.J.; Liable-Sands, L.M.; Rheingold, A.L. Approaches to Alkaline Earth Metal-Organic Chemical Vapor Deposition Precursors. Synthesis and Characterization of Barium Fluoro-Ketoiminate Complexes Having Appended Polyether "Lariats", Inorg. Chem., 1998, 37, 5625.
  • Kaatz, F.H.; Markworth, P.R.; Dai, J.Y.; Buchholz, D.B.; Xiu, X.; Chudzik, M.; Belot, J.A.; Kannewurf, C.R.; Marks, T.J.; Chang, R.P.H. Stability of Bilayer Films of YBa2Cu3O7 and YSZ Grown on LAO by Chemical Vapor Deposition, Advan. Mater. (Chem. Vap. Depos.), 1998, 4, 99.
  • Wang, A.; Dai, J.; Cheng, J.; Chudzik, M.P.; Marks, T.J.; Chang, R.P.H.; Kannewurf, C.R. Charge Transport, Optical Transparency, Microstructure, and Processing Relationships in Transparent Conductive Indium-Zinc Oxide Films Grown By Low Pressure Metal-Organic Chemical Vapor Deposition, Appl. Phys. Lett., 1998, 73, 327.
  • Yan, Y.; Pennycook, S.J.; Dai, J.; Chang, R.P.H.; Wang, A.; Marks, T.J. Polytypoid Structures in Annealed In2O3-ZnO Films, Appl. Phys. Lett. 1998, 73, 2585.
  • McNeely, R.J.; Belot, J.A., Schindler, J.L.; Chudzik, M.P.; Kannewurf, C.R.; Zhang, X.F.; Miller, D.J.; Marks, T.J. Novel Metal-Organic Chemical Vapor Deposition/TIF Annealing Route to Thin Films of Tl1Ba2Ca2Cu3O9+x, J. Supercond. 1998, 11, 133.
 

D-Team

  • Letizia, J.A.; Rivnay, J.; Facchetti, A.; Ratner, M.A.; Marks, T.J. Thermally-Activated Mobility Analysis of n-Channel, p-Channel, and Ambipolar Organic Field Effect Transistors, submitted for publication.
  • Jeong, Y.T.; Lewis, S.D.; Cobb, B.H.; Dodabalapur, A.; Facchetti, A.; Marks, T.J. Realization of Dual-Channel Organic Field-Effect Transistors and Their Applications to Chemical Sensing, submitted for publication.
  • Ortiz, R.P.; Casado, J.; Hernandez, V.; Lopez Navarrete, J.T.; Letizia, J.A.; Facchetti, A.; Ratner, M.A.; Marks, T.J. Thiophene-Diazine Molecular Semiconductors.  Synthesis, Structural, Electrochemical, Optical and Electronic Structural Properties, and Implementation in Organic Field-Effect Transistors, submitted for publication.
  • Kim, H.S.; Byme, P.D.; Facchetti, A.; Marks, T.J. High Performance Solution-Processed Indium Oxide Thin-Film Transistors, J. Am. Chem. Soc., in press.
  • Ortiz, R.P.; Facchetti, A.; Marks, T.J.; Casado, J.; Zgierski, M.Z. Ambipolar Organic Field-Effect Transistors from Cross-Conjugated Aromatic Quaterthiophenes.  Comparisons with Quinoidal Parent Materials, submitted for publication.
  • Usta, H.; Facchetti, A.; Marks, T. Air-Stable, Solution-Processable n-Channel and Ambipolar Semiconductors for Thin-Film Transistors Based on the Indenofluorenebis(dicyanovinylene) Core, J. Am. Chem. Soc., 2008, 130, 8580-8581.
  • DiBenedetto, S.A.; Frattarelli, D.; Ratner, M.A.; Facchetti, A.; Marks, T.J. Vapor Phase Self-Assembly of Molecular Gate Dielectrics for Thin Film Transistors, J. Amer. Chem. Soc., 2008, 130, 7528-7529.
  • Kim, C.; Wang, Z.; Choi, H.-J.; Ha, Y.-G.; Facchetti, A.; Marks, T.J. Printable Crosslinked Polymer Blend Dielectrics.  Design Strategies, Synthesis, Microstructures, and Electrical Properties, with Organic Field-Effect Transistors as Testbeds, J. Am. Chem. Soc., 2008, 130, 6867-6878.
  • Risko, C.; Zangmeister, C.D.; Yao, Y.; Marks, T.J.; Tour, J.M.; Ratner, M.A.; van Zee R.D. Experimental and Theoretical Indentification of Valence Energy Levels and Interface Dipole Trends for a Family of (Oligo)Phenylene-Ethynylenethiols Adsorbed on Gold, J. Phys. Chem. C, in press.
  • Usta, H.; Facchetti, A.; Marks, T.J. Synthesis and Characterization of Electron-Deficient and Highly Soluble (Bis)Indenofluorene Building Blocks for n-Type Semiconducting Polymers, Organic Letters, 2008, 10, 1385-1388.
  • Chen, M.-C.; Kim, C.; Chen, S.-Y.; Chiang, Y.-J.; Chung, M.-C.; Facchetti, A.; Marks, T.J. Functionalized Anthradithiophenes for Organic Field-Effect Transistors, J. Mater. Chem., 2008, 18, 1029-1036.
  • Letizia, J.A.; Salata, M.R.; Tribout, C.M.; Facchetti, A.; Ratner, M.A.; Marks, T.J. n-Channel Polymers by Design:  Optimizing the Interplay of Solubilizing Substituents, Crystal Packing, and Field-Effect Transistor Characteristics in Polymeric Bithiophene-Imide Semiconductors, J. Am. Chem. Soc., in press.
  • Facchetti, A.; Ju, S.; Janes, D.; Jones, B.; Wasielewski, M.; Marks, T.J. Organic-Inorganic Flexible and Transparent Electronics, IEEE Electron Device Letters, in press.
  • Wang, L.; Yoon, M.-H.; Facchetti, A.; Marks, T.J. Flexible Thin-Film Transistors Using All-Transparent Component Materials, Advanced Materials, 2007, 19, 3252-3256.
  • Ju, S.; Kim, S.; Ha, Y.-G.; Facchetti, A.; Mohammadi, S.; Marks, T.J.; Janes, D.B. Interface Studies of ZnO Nanowire Transistors Using Low-Frequency Noise and Temperature-Dependent I-V Measurements, Appl. Phys. Lett., 2008, 92, 022104.
  • Jones, B.A.; Facchetti, A.; Wasielewski, M.R.; Marks, T.J. Effects of Arylene Diimide Thin Film Growth Conditions on n-Channel OFET Performance, Advan. Funct. Mater., 2008, 18, 1-11.
  • Koh, S.E.; Letizia, J.A.; Facchetti, A.; Marks, T.J.; Ratner, M.A. Electronic Structure of High Mobility Phenacyl- and Perfluorophenacyl-Tetrathiophene Semiconductors.  Understanding  p-Type versus n-type Transport Properties, submitted for publication.
  • Jones, B.A.; Facchetti, A., Wasielewski, M.R.; Marks, T.J. High Mobility Air-Stable n-Type Perylene Diimide Semiconductors.  Insight Into Materials Design for Stability of n-Type Charge Transport, J. Am. Chem. Soc., 2007, 129, 15259-15278.
  • Ju, S.; Li, J.; Liu, J.; Chen, P.-C.; Ha, Y.-G.; Zhou, C.; Facchetti, A.; Janes, D.B.; Marks, T.J. Transparent Active Matrix Organic Light-Emitting Diode Displays Driven By Nanowire Transistor Circuitry, Nano Letters, 2008, 8, 997-1004.
  • Yan, H.; Lu, S.; Zheng, Y.; Inagaki, P.; Facchetti, A.; Marks, T.J. High Mobility Solution-Processed n-Channel Organic Thin Film Transistors, SPIE Proc., 6658, 6658S-1 – 6658S-8.
  • Byrne, P.D.; Facchetti, A.; Marks, T.J. Solution-Processed High-Mobility CdSe Thin-Film Transistors with a Self-Assembled Molecular Multilayer Gate Dielectric, Advanced Materials, 2008, 20, 1-6.
  • Lu, G.; Usta, H.; Risko, C.; Wang, L.; Facchetti, A.; Ratner, M.A. Marks, T.J. Synthesis, Characterization, and Field-Effect Transistor Response of Semiconducting Silole Polymers with Excellent Hole Mobility and Air Stability, Experiment and Theory, J. Am. Chem. Soc., 2008, 130, 7670-7685.
  • Capelli, R.; Dinelli, F.; Toffanin, S.; Todescato, F.; Murgia, M.; Muccini, M.; Facchetti, A.; Marks, T.J. Organic Light-Emitting Transistors Based on Intrinsically Ambipolar Small Molecules, J. Phys. Chem. B, in press.
  • Koh, S.E.; Risko, C.; da Silva Filho, D.A.; Kwon, O.; Facchetti, A.; Bredas, J.-L.; Marks, T.J.; Ratner, M.A. Modeling Electron and Hole Transport in Perfluorinated-Oligothiopene Semiconductors:  Investigation of Geometric and Electronic Structure Properties, Advan. Funct. Mater., 2008, 18, 332-340.
  • Yoo, B.; Basu, D.; Jung, T.; Fine, D.; Jones, B.A.; Facchetti, A.; Wasielewski, M.R.; Marks, T.J.; Dimmler, K.; Dodabalapur, A. Organic Complementary Circuits Using Solution Deposited Active Semiconductors, Advanced Materials, 2007, 19, 4028-4032.
  • Kim, C.; Facchetti, A.; Marks, T.J. Polymer Gate Dielectric Surface Viscoelasticity Strongly Modulates Pentacene Transistor Performance, Science, 2007, 318, 76-80.
  • Koh, S.E.; Grozema, F.; Facchetti, A.; Ratner, M.A.; Marks, T.J. Hydrogen-Bonding as a Self-Assembling Architecture for Conducting Oligothiophenes, submitted for publication.
  • Koh, S.E.; Stenger-Smith, J.D.; Facchetti, A.; Irvin, D.J.; Irvin, J.A.; Ratner, M.A.; Marks, T.J. Polythiophene-Based Semiconductors as Electron Transporters in Polymer-Based Electrochemical Supercapacitors, J. Electrochem. Soc., in press.
  • Lin, H.C.; Kim, S.K.; Chang, D.; Xuan, Y.; Mohammadi, S.; Ye, P.D. Direct-Current and Radio-Frequency Characterization of GaAs Metal-Insulator-Semiconductor Field-Effect-Transistors Enabled by Self-Assembled Nanodielectrics, Appl. Phys. Lett., 2007, 91, 092103.
  • Wang, Z.; Kim, C.; Facchetti, A.; Marks, T.J. Anthrecenedicarboximides As Novel N-Channel Semiconductors for Thin-Film Transistors, J. Amer. Chem. Soc., 2007, 129, 13362-13363.
  • Lee, K.; Janes, D.B.; Lu, G.; Facchetti, A.; Marks, T.J. GaAs Junction Field Effect Transistors Passivated with Self-Assembled Mono- and Multilayers, Appl. Phys. Lett., 2008, 123509.
  • Ju, S.; Facchetti, A.; Xuan, Y.; Liu, J.; Ishikawa, F.; Ye, P.; Zhou, C.; Marks, T.J.; Janes, D.B. Fabrication of Fully Transparent In2O3 and ZnO Nanowire Transistors for Invisible and Flexible Electronics, Nature Nanotechnology, 2007, 2, 378-384.
  • Kim, C.; Facchetti, A.; Marks, T.J. Gate Dielectric Chemical Control of Pentacene Film Microstructure and Field-Effect Transistor Performance, Advanced Materials, Advanced Materials, 2007, 19, 2561-2566.
  • Jones, B.A.; Facchetti, A.; Marks, T.J.; Wasielewski, M.R., Air-Stable n-Type Cyanonaphthalene Dimide Semiconductors for Flexible, Optically-Transparent Organic Transistors, Chem. Mater., 2007, 19, 2703-2705.
  • Ju, S.; Janes, D.B.; Lu, G.; Facchetti, A.; Marks, T.J. Effects of Bias Stress on ZnO Nanowire Field-Effect Transistors Fabricated with Organic Gate Nanodielectrics, Appl. Phys. Lett., 2006, 89, 193506-193508.
  • Lin, H.C.; Ye, P.D.; Xuan, Y.; Lu, G.; Facchetti, A.; Marks, T.J. High-Performance GaAs Metal-Insulator-Semiconductor Field-Effect-Transistors Enabled By Self-Assembled Nanodielectrics, Appl. Phys. Lett., 2006, 89, 142101-142103.
  • DiBenedetto, S.A.; Paci, I.; Facchetti, A.; Marks, T.J.; Ratner, M.A. High-Capacitance Organic Nanodielectrics. Effective Medium Models of Their Response, J. Phys. Chem. B., 2006, 110, 22394-22399.
  • Koh, S.E.; Medvedeva, J.E.; Facchetti, A.; Delley, B.; Freeman, A.J.; Marks, T.J.; Ratner, M.A. Quantum Chemical Analysis of Electronic Structure and Charge Transport in Perfluoroarene-Modified Oligothiophene Semiconductors, J. Phys. Chem. B., 2006, 110, 24361-24370.
  • Yoon, M.-H.; DiBenedetto, S.A.; Russell, M.T.; Facchetti, A.; Marks, T.J. High-Performance n-Type Organic Semiconductors Based on Carbonyl-Functionalized Quaterthiophenes: Thin-Film Transistor Response and Majority Charge Carrier Type Inversion via Protection/Deprotection, Chem. Mater., 2007, 19, 4864-4881.
  • Ju, S.; Lee, K; Yoon, M.-H.; Facchetti, A.; Marks, T.J.; Janes, D.B. High-Performance ZnO Nanowire Field-Effect Transistors with Organic Nanodielectrics:  Effects of Metal Contacts and Ozone Treatment, Nanotechnology, 2007, 18, 155201.
  • Ju, S.; Lee, K.; Janes, D.B.; Dwivedi, R.C.; Baffour-Awuah, H.; Wilkins, R.; Yoon, M.-H.; Facchetti, A.; Marks, T.J. Remarkable Radiation Hardness of Single Nanowire Transistors Using Robust Organic Gate Nanodielectrics. A Total-Integrated-Dose Proton Radiation Study, Appl. Phys. Lett., 2006, 89, 073510-1-3.
  • Yoon, M.-H.; Kim, C.; Facchetti, A.; Marks, T.J. Gate Dielectric Chemical Structure-Organic Field-Effect Transistor Performance Correlations for Electron, Hole, and Ambipolar Semiconductors, J. Am. Chem. Soc., 2006, 128, 12851-12869.
  • Dholakia, G.R.; Meyyappan, M.; Facchetti, A.; Marks, T.J. Monolayer to Multilayer Nanostructural Growth Transistion in n-Type Oligothiophenes and Implications for Electronic Transport, NanoLetters, 2006, 6, 2447-2455.
  • Wang, L.; Yoon, M.-H.; Lu, G.; Facchetti, A.; Yang, Y.; Marks, T.J. High-Performance Transparent Inorganic-Organic Hybrid Thin-Film Transistors Fabricated at Room Temperature. Towards Large-Scale Invisible Electronics, Nature Mater., 2006, 5, 893-900.
  • Usta, H.; Lu, G.; Facchetti, A.; Marks, T.J. Silolearene-Thiophene Copolymers as Semiconductors for Organic Thin-Film Transistors, J. Am. Chem. Soc., 2006, 128, 9034-9035.
  • Yoo, B.; Madgavkar, A.; Jones, B.A.; Nadkarni, S.; Facchetti, A.; Kimmler, K.; Wasielewski, M.R.; Marks, T.J.; Dodabalapur, A. Organic Complementary D Flip-Flops Enabled by Perylene Diimides and Pentacene, IEEE Electron Device Letters I, 2006, 27, 737-739.
  • Jung, T.; Yoo, B.; Wang, L.; Dodabalapur, A.; Jones, B.A.; Faccetti, A.; Wasielewski, M.R.; Marks, T.J. Nanoscale n-Channel and Ambipolar Organic Field-Effect Transistors, Appl. Phys. Lett., 2006, 88, 183102.
  • Dinelli, F.; Capelli, R.; Loi, M.A.; Murgia, M.; Muccini, M.; Facchetti, A.; Marks, T.J. High Ambipolar Mobility in Organic Light-Emitting Transistors, Advanced Materials, 2006, 18, 1416-1420.
  • Yoo, B.; Jung, T.; Basu, D.; Dodabalapur, A.; Jones, B.A.; Facchetti, A.; Wasielewski, M.R.; Marks, T.J. High Mobility Bottom-Contact n-Channel Organic Transistors and Their Use In Complementary Ring Oscillators, Appl. Phys. Lett., in press.
  • Hutchison, G.R.; Ratner, M.A.; Marks, T.J. Intermolecular Charge Transfer of Heterocyclic Oligomers. Effects of Heteroatom and Orientation on Hopping Transport in Organic Semiconductors, J. Am. Chem. Soc., 2005, 127, 16866-16881.
  • Yoon, M.-H.; Facchetti, A.; Marks, T.J. Molecular Dielectric Multilayers for Ultra-Low-Voltage Organic Thin Film Transistors, MRS Symposium Proceedings, 2005, 871E, I3.2.1-I3.2.6.
  • Ju, S.; Lee, K.; Janes, D.B.; Yoon, M.-H.; Facchetti, A.; Marks, T.J. Low Operating Voltage ZnO Nanowire Field-Effect Transistors Enabled by Self-Assembled Organic Gate Nanodielectrics, Nano Letters, 2005, 5, 2281-2286.
  • Letizia, J.A.; Facchetti, A.; Stern, C.L.; Ratner, M.A.; Marks, T.J. High Electron Mobility in Solution-Cast and Vapor-Deposited Phenacyl-Quaterthiophene Based Field-Effect Transistors: Toward N-Type Polythiophenes, J. Am. Chem. Soc., 2005, 127, 13476-13477.
  • Hur, S.-H.; Yoon, M.-H.; Gaur, A.; Facchetti, A.; Marks, T.J.; Rogers, J.A. Organic Nanodielectrics for Low Voltage Carbon Nanotube Thin Film Transistors and Complementary Logic Gates, J. Am. Chem. Soc., 2005, 127, 13808-13809.
  • Yan, H.; Yoon, M.-H.; Facchetti, A.; Marks, T.J. Low-Threshold Top-Gate Organic Field-Effect Transistors Enabled by a Crosslinkable Polymer Blend as the Semiconducting Layer, Appl. Phys. Lett., 2005, 87, 183501-183504.
  • Facchetti, A.; Yoon, M.-H.; Marks, T.J. Gate Dielectrics for Organic Field-Effect Transistors. New Opportunities for Organic Electronics, Advanced Materials, 2005, 17, 1705-1725.
  • Li, Q.; Kumar, V.; Li, Y.; Zhang, H.; Marks, T.J.; Chang, R.P.H. Fabrication of ZnO Nanorods and Nanotubes in Aqueous Solutions, Chem. Mater., 2005, 17, 1001-1006.
  • Casado, J.; Hernandez, V.; Ruiz Delgado, M.C.; Ortiz, R.P.; Lopez Navarrete, J.T.; Facchetti, A.; Marks, T.J. Incisive Structure-Spectroscopic Correlation in Oligothiophenes Functionalized with (") Inductive/Mesomeric Fluorine Groups. Joint Raman and DFT Study, J. Amer. Chem. Soc., 2005, 127, 13364-13372.
  • Yoon, M.-H.; Yan, H.; Facchetti, A.; Marks. T.J. Low-Voltage Organic Field-Effect Transistors and Inverters Enabled by Ultra-Thin Crosslinked Polymers as the Gate Insulator, J. Am. Chem. Soc., in press.
  • Yoon, M.-H.; DiBenedetto, S.; Facchetti, A.; Marks, T.J. Organic Thin-Film Transistors Based on Carbonyl-Functionalized Quaterthiophenes.  High Mobility N-Channel Semiconductors and Ambipolar Transport, J. Am. Chem. Soc., 2005, 127, 1348-1349.
  • Hutchison, G.R.; Ratner, M.A.; Marks, T.J. Hopping Transport in Electrically Conductive Heterocyclic Oligomers:  Reorganization Energies and Substituent Effects, J. Am. Chem. Soc., 2005, 127, 2339-2350.
  • Jones, B.A.; Ahrens, M.J.; Yoon, M.-H.; Facchetti, A.; Marks, T.J. Wasielewski, M.R. Dicyano- Perylene-3,4:9,10-bis(dicarboximides) as High-Mobility Air-Stable n-Type Semiconductors with Processing Versatility, Angew. Chem. Int. Ed. Engl., 2004, 43, 6363-6366.
  • Facchetti, A.; Letizia, J.; Yoon, M.-H.; Mushrush, M.; Katz, H.E.; Marks, T.J. Synthesis and Characterization of Diperfluorooctyl-Substituted Phenylene-Thiophene Oligomers as N-type Semiconductors.  Molecular Structure-Film Microstructure-Mobility Relationships, Organic Field-Effect Transistors and Transistor Nonvolatile Memory Elements, Chem. Mater., 2004, 16, 4715-4727.
  • Facchetti, A.; Mushrush, M.; Yoon, M.-H.; Hutchison, G.R.; Ratner, M.A.; Marks, T.J. Building Blocks for N-Type Molecular and Polymeric Electronics.  Perfluoroalkyl- Versus Alkyl-Functionalized Oligothiophenes (nT; n = 2 – 6).  Systematics of Thin Film Microstructure, Semiconductor Performance, and Modeling of Majority Charge Injection in Field-Effect Transistors, J. Am. Chem. Soc., 2004, 126, 13859-13874.
  • Facchetti, A.; Yoon, M.-H.; Stern, C.L.; Hutchison, G.R.; Ratner, M.A.; Marks, T.J. Building Blocks for N-Type Molecular and Polymeric Electronics.  Perfluoroalkyl- Versus Alkyl- Functionalized Oligothiophenes (nTs; n = 2 – 6).  Systematic Synthesis, Spectroscopy, Electrochemistry, and Solid State Organization, J. Am. Chem. Soc., 2004, 126, 13480-13501.
  • Keinan, S.; Ratner, M.A.; Marks, T.J. Molecular Zippers Designing a Supramolecular System, Chem. Phys. Lett., 2004, 392, 291-296.
  • Facchetti, A.; Hutchison, G.; Yoon, M-H.; Letizia, J.; Ratner, M.A.; Marks, T.J. Strategies for n-Type Molecular and Polymeric Electrical Conductors. Design, Synthesis, and Characterization, Polymer Preprints, 2004, 45(1), 185.
  • Hutchison, G.R.; Ratner, M.A.; Marks, T.J. Electronic Structure and Band Gaps in Cationic Heterocyclic Oligomers.  Multidimensional Analysis of the Interplay of Heteroatoms, Substituents, Molecular Length, and Charge on Redox and Transparency Characteristics, J. Phys. Chem., in press.
  • Facchetti, A.; Marks, T.J.; Katz, H.E.; Veinot, J. Organic Semiconductor Materials, in Gamota, D.E.; Brazis, P.; Kalyanasundaram, K.; Zhang, J., Eds., Printed Organic and Molecular Electronics, Kluwer: Boston, 2004, Chapt. 2.
  • Facchetti, A.; Yoon, M.-H.; Stern, C.L.; Katz, H.E.; Marks, T.J. Building Blocks for n-Type Organic Electronics. Regiochemically Controlled Inversion of Majority Carrier Sign in Perfluoroarene-Modified Thiophene Oligomers, Angew. Chem. Int. Ed., 2003, 42, 3900-3903.
  • Hutchison, G.R.; Zhao, Y.-J.; Freeman, A.J.; Ratner, M.A.; Marks, T.J. Electronic Structure of Conducting Polymers: Limitations of Oligomer Extrapolation Approximations and Effects of Heteroatoms, Phys. Rev. B, 2003, 68, 035204.
  • Mushrush, M.A.; Facchetti, A.; Lefenfeld, M.; Katz, H.E.; Marks, T.J. Solution-Processable Phenylene-Thiophene-Based Organic Field-Effect Transistors and Nonvolatile Transistor Memory Elements, J. Am. Chem. Soc., 2003, 125, 9414-9423.
  • Facchetti, A.; Yoon, M.-H.; Stern, C.L.; Katz, H.E.; Marks, T.J. Building Blocks for n-Type Organic Electronics. Regiochemically Controlled Inversion of Majority Carrier Sign in Perfluoroarene-Modified Thiophene Oligomers, Angew. Chem. Int. Ed., 2003, 42, 3900-3903.
  • Facchetti, A.; Mushrush, M.; Katz, H.E.; Marks, T.J. N-Type Building Blocks for Organic Electronics. A Homologous Family of Fluorocarbon- Substituted Thiophene Oligomers with High Carrier Mobility, Advan. Mater., 2003, 15, 33-38.
  • Hutchison, Geoffrey R.; Ratner, Mark A.; Marks, Tobin J. Accurate Prediction of Band Gaps in Neutral Heterocyclic Conjugated Polymers. Journal of Physical Chemistry A 2002, 106, 10596-10605.
  • Hutchison, G.R.; Ratner, M.A.; Marks, T.J., R. Naaman, Adsorption of Polar Molecules on a Molecular Surface, J. Phys. Chem., 2001, 105, 2881-2884.
  • Facchetti, A.; Wang, A.; Marks, T.J.; Sirringhaus, H.; Deng, Y.; Friend, R.H. Tuning Sexithiophene Semiconducting Properties by alpha,omega-Substitution. alpha,omega-Diperfluorohexylsexithiophene. The First n-Type Sexithiophene for Thin Film Transistors, Angew. Chem. Int. Ed., Engl., 2000, 39, 4547-4551.
  • Facchetti, A.; Wang, A.; Marks, T.J.; Sirringhaus, H.; Deng, Y.; Friend, R.H., Diperfluorohexylsexithiophene. Synthesis, Characterization, and Thin-Film Properties for the First n-Type Sexithiophene for Thin Film Transistors, Polymer Mat. Sci. Eng., 2000, 83 (2), 290.